[(Z)-O-Methyl N-(3-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)

Two independent mol­ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo­hexyl groups as well as the benzene ring. In each mol­ecule, the Au atom is coordinated within a S,P-donor set that defines...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983779/
https://www.ncbi.nlm.nih.gov/pubmed/21580538
http://dx.doi.org/10.1107/S1600536810010445
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description Two independent mol­ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo­hexyl groups as well as the benzene ring. In each mol­ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 175.10 (5) and 177.26 (5)° for the two mol­ecules], with the distortion due in part to the close intra­molecular approach of the O atom [Au⋯O contacts = 3.054 (4) and 3.013 (4) Å, respectively, for the two mol­ecules].
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spelling pubmed-29837792010-12-30 [(Z)-O-Methyl N-(3-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I) Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers Two independent mol­ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo­hexyl groups as well as the benzene ring. In each mol­ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = 175.10 (5) and 177.26 (5)° for the two mol­ecules], with the distortion due in part to the close intra­molecular approach of the O atom [Au⋯O contacts = 3.054 (4) and 3.013 (4) Å, respectively, for the two mol­ecules]. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2983779/ /pubmed/21580538 http://dx.doi.org/10.1107/S1600536810010445 Text en © Tadbuppa and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-O-Methyl N-(3-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title [(Z)-O-Methyl N-(3-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full [(Z)-O-Methyl N-(3-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_fullStr [(Z)-O-Methyl N-(3-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_full_unstemmed [(Z)-O-Methyl N-(3-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_short [(Z)-O-Methyl N-(3-chloro­phen­yl)thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I)
title_sort [(z)-o-methyl n-(3-chloro­phen­yl)thio­carbamato-κs](tricyclo­hexyl­phosphine-κp)gold(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983779/
https://www.ncbi.nlm.nih.gov/pubmed/21580538
http://dx.doi.org/10.1107/S1600536810010445
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AT tiekinkedwardrt zomethyln3chlorophenylthiocarbamatokstricyclohexylphosphinekpgoldi

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