1-{[(Cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2H-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl­ate

In the title compound, C(33)H(34)N(6)O(6), the dihydro­benzimidazol-2-one ring system is essentially planar (r.m.s. deviation = 0.021 Å). The cyclo­hexane ring adopts a chair conformation. In the 5-(biphenyl-2-yl)-2H-tetra­zole fragment, the tetra­zole ring is twisted away from the attached benzene...

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Detalles Bibliográficos
Autores principales: Mohan, A., Ramesh, P., Saravanan, D., Ponnuswamy, M. N.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983784/
https://www.ncbi.nlm.nih.gov/pubmed/21580794
http://dx.doi.org/10.1107/S1600536810011049
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author Mohan, A.
Ramesh, P.
Saravanan, D.
Ponnuswamy, M. N.
author_facet Mohan, A.
Ramesh, P.
Saravanan, D.
Ponnuswamy, M. N.
author_sort Mohan, A.
collection PubMed
description In the title compound, C(33)H(34)N(6)O(6), the dihydro­benzimidazol-2-one ring system is essentially planar (r.m.s. deviation = 0.021 Å). The cyclo­hexane ring adopts a chair conformation. In the 5-(biphenyl-2-yl)-2H-tetra­zole fragment, the tetra­zole ring is twisted away from the attached benzene ring by 35.73 (11)° and the two benzene rings form a dihedral angle of 68.00 (9)°. An intra­molecular C—H⋯O inter­action is observed. In the crystal, the mol­ecules are linked into a zigzag chain running along the b axis by inter­molecular N—H⋯O hydrogen bonds.
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spelling pubmed-29837842010-12-30 1-{[(Cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2H-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl­ate Mohan, A. Ramesh, P. Saravanan, D. Ponnuswamy, M. N. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(33)H(34)N(6)O(6), the dihydro­benzimidazol-2-one ring system is essentially planar (r.m.s. deviation = 0.021 Å). The cyclo­hexane ring adopts a chair conformation. In the 5-(biphenyl-2-yl)-2H-tetra­zole fragment, the tetra­zole ring is twisted away from the attached benzene ring by 35.73 (11)° and the two benzene rings form a dihedral angle of 68.00 (9)°. An intra­molecular C—H⋯O inter­action is observed. In the crystal, the mol­ecules are linked into a zigzag chain running along the b axis by inter­molecular N—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983784/ /pubmed/21580794 http://dx.doi.org/10.1107/S1600536810011049 Text en © Mohan et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mohan, A.
Ramesh, P.
Saravanan, D.
Ponnuswamy, M. N.
1-{[(Cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2H-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl­ate
title 1-{[(Cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2H-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl­ate
title_full 1-{[(Cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2H-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl­ate
title_fullStr 1-{[(Cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2H-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl­ate
title_full_unstemmed 1-{[(Cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2H-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl­ate
title_short 1-{[(Cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2H-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1H-benzimidazole-4-carboxyl­ate
title_sort 1-{[(cyclo­hexyl­oxy)carbon­yl]­oxy}ethyl 3-{[2′-(2-ethyl-2h-tetra­zol-5-yl)biphenyl-4-yl]meth­yl}-2-oxo-2,3-dihydro-1h-benzimidazole-4-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983784/
https://www.ncbi.nlm.nih.gov/pubmed/21580794
http://dx.doi.org/10.1107/S1600536810011049
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AT rameshp 1cyclohexyloxycarbonyloxyethyl322ethyl2htetrazol5ylbiphenyl4ylmethyl2oxo23dihydro1hbenzimidazole4carboxylate
AT saravanand 1cyclohexyloxycarbonyloxyethyl322ethyl2htetrazol5ylbiphenyl4ylmethyl2oxo23dihydro1hbenzimidazole4carboxylate
AT ponnuswamymn 1cyclohexyloxycarbonyloxyethyl322ethyl2htetrazol5ylbiphenyl4ylmethyl2oxo23dihydro1hbenzimidazole4carboxylate

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