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Diaquabis(5-bromo-2-hydroxybenzoato)bis(N-methylnicotinamide)zinc(II)
The title mononuclear complex molecule, [Zn(C(7)H(4)BrO(3))(2)(C(7)H(8)N(2)O)(2)(H(2)O)(2)], has a crystallographically imposed centre of symmetry. The zinc(II) atom is coordinated by two N atoms from two N-methylnicotinamide ligands, two O atoms from two 5-bromosalicylate anions and two aqua O a...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983787/ https://www.ncbi.nlm.nih.gov/pubmed/21580499 http://dx.doi.org/10.1107/S1600536810008834 |
Sumario: | The title mononuclear complex molecule, [Zn(C(7)H(4)BrO(3))(2)(C(7)H(8)N(2)O)(2)(H(2)O)(2)], has a crystallographically imposed centre of symmetry. The zinc(II) atom is coordinated by two N atoms from two N-methylnicotinamide ligands, two O atoms from two 5-bromosalicylate anions and two aqua O atoms in a slightly distorted octahedral geometry. Intramolecular O—H⋯O hydrogen-bonding interactions are present. In the crystal structure, molecules are linked by intermolecular O—H⋯O and N—H⋯O hydrogen bonds, forming a two-dimensional network perpendicular to [100]. |
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