Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II)

The title mononuclear complex mol­ecule, [Zn(C(7)H(4)BrO(3))(2)(C(7)H(8)N(2)O)(2)(H(2)O)(2)], has a crystallographically imposed centre of symmetry. The zinc(II) atom is coordinated by two N atoms from two N-methyl­nicotinamide ligands, two O atoms from two 5-bromo­salicylate anions and two aqua O a...

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Detalles Bibliográficos
Autores principales: Bujdošová, Zuzana, Kuchár, Juraj, Györyová, Katarína
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983787/
https://www.ncbi.nlm.nih.gov/pubmed/21580499
http://dx.doi.org/10.1107/S1600536810008834
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author Bujdošová, Zuzana
Kuchár, Juraj
Györyová, Katarína
author_facet Bujdošová, Zuzana
Kuchár, Juraj
Györyová, Katarína
author_sort Bujdošová, Zuzana
collection PubMed
description The title mononuclear complex mol­ecule, [Zn(C(7)H(4)BrO(3))(2)(C(7)H(8)N(2)O)(2)(H(2)O)(2)], has a crystallographically imposed centre of symmetry. The zinc(II) atom is coordinated by two N atoms from two N-methyl­nicotinamide ligands, two O atoms from two 5-bromo­salicylate anions and two aqua O atoms in a slightly distorted octa­hedral geometry. Intra­molecular O—H⋯O hydrogen-bonding inter­actions are present. In the crystal structure, mol­ecules are linked by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming a two-dimensional network perpendicular to [100].
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spelling pubmed-29837872010-12-30 Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II) Bujdošová, Zuzana Kuchár, Juraj Györyová, Katarína Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title mononuclear complex mol­ecule, [Zn(C(7)H(4)BrO(3))(2)(C(7)H(8)N(2)O)(2)(H(2)O)(2)], has a crystallographically imposed centre of symmetry. The zinc(II) atom is coordinated by two N atoms from two N-methyl­nicotinamide ligands, two O atoms from two 5-bromo­salicylate anions and two aqua O atoms in a slightly distorted octa­hedral geometry. Intra­molecular O—H⋯O hydrogen-bonding inter­actions are present. In the crystal structure, mol­ecules are linked by inter­molecular O—H⋯O and N—H⋯O hydrogen bonds, forming a two-dimensional network perpendicular to [100]. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2983787/ /pubmed/21580499 http://dx.doi.org/10.1107/S1600536810008834 Text en © Bujdošová et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bujdošová, Zuzana
Kuchár, Juraj
Györyová, Katarína
Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II)
title Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II)
title_full Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II)
title_fullStr Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II)
title_full_unstemmed Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II)
title_short Diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(N-methyl­nicotinamide)zinc(II)
title_sort diaqua­bis(5-bromo-2-hydroxy­benzoato)bis­(n-methyl­nicotinamide)zinc(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983787/
https://www.ncbi.nlm.nih.gov/pubmed/21580499
http://dx.doi.org/10.1107/S1600536810008834
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