(1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate

In the title compound, [Li(C(8)H(16)O(4))(CD(3)CN)]ClO(4), the Li atom is penta­coordinate. The O atoms of the 12-crown-4 ether form the basal plane, whereas the N atom of the trideutero­aceto­nitrile occupies the apical position. The Li(+) atom is displaced by 0.794 (6) Å toward the apical position...

Descripción completa

Detalles Bibliográficos
Autores principales: Guzei, Ilia A., Spencer, Lara C., Xiao, Lingyun, Burnette, Ronald R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983791/
https://www.ncbi.nlm.nih.gov/pubmed/21580532
http://dx.doi.org/10.1107/S1600536810009530
Descripción
Sumario:In the title compound, [Li(C(8)H(16)O(4))(CD(3)CN)]ClO(4), the Li atom is penta­coordinate. The O atoms of the 12-crown-4 ether form the basal plane, whereas the N atom of the trideutero­aceto­nitrile occupies the apical position. The Li(+) atom is displaced by 0.794 (6) Å toward the apical position from the plane formed by the O atoms because the Li(+) atom is too large to fit in the cavity of the 12-crown-4 ether, resulting in a distorted square-pyramidal geometry about the Li(+) atom.

Ejemplares similares