(1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate

In the title compound, [Li(C(8)H(16)O(4))(CD(3)CN)]ClO(4), the Li atom is penta­coordinate. The O atoms of the 12-crown-4 ether form the basal plane, whereas the N atom of the trideutero­aceto­nitrile occupies the apical position. The Li(+) atom is displaced by 0.794 (6) Å toward the apical position...

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Detalles Bibliográficos
Autores principales: Guzei, Ilia A., Spencer, Lara C., Xiao, Lingyun, Burnette, Ronald R.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983791/
https://www.ncbi.nlm.nih.gov/pubmed/21580532
http://dx.doi.org/10.1107/S1600536810009530
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author Guzei, Ilia A.
Spencer, Lara C.
Xiao, Lingyun
Burnette, Ronald R.
author_facet Guzei, Ilia A.
Spencer, Lara C.
Xiao, Lingyun
Burnette, Ronald R.
author_sort Guzei, Ilia A.
collection PubMed
description In the title compound, [Li(C(8)H(16)O(4))(CD(3)CN)]ClO(4), the Li atom is penta­coordinate. The O atoms of the 12-crown-4 ether form the basal plane, whereas the N atom of the trideutero­aceto­nitrile occupies the apical position. The Li(+) atom is displaced by 0.794 (6) Å toward the apical position from the plane formed by the O atoms because the Li(+) atom is too large to fit in the cavity of the 12-crown-4 ether, resulting in a distorted square-pyramidal geometry about the Li(+) atom.
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spelling pubmed-29837912010-12-30 (1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate Guzei, Ilia A. Spencer, Lara C. Xiao, Lingyun Burnette, Ronald R. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Li(C(8)H(16)O(4))(CD(3)CN)]ClO(4), the Li atom is penta­coordinate. The O atoms of the 12-crown-4 ether form the basal plane, whereas the N atom of the trideutero­aceto­nitrile occupies the apical position. The Li(+) atom is displaced by 0.794 (6) Å toward the apical position from the plane formed by the O atoms because the Li(+) atom is too large to fit in the cavity of the 12-crown-4 ether, resulting in a distorted square-pyramidal geometry about the Li(+) atom. International Union of Crystallography 2010-03-24 /pmc/articles/PMC2983791/ /pubmed/21580532 http://dx.doi.org/10.1107/S1600536810009530 Text en © Guzei et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Guzei, Ilia A.
Spencer, Lara C.
Xiao, Lingyun
Burnette, Ronald R.
(1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate
title (1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate
title_full (1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate
title_fullStr (1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate
title_full_unstemmed (1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate
title_short (1,4,7,10-Tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate
title_sort (1,4,7,10-tetra­oxacyclo­dodeca­ne)(trideuteroacetonitrile)lithium perchlorate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983791/
https://www.ncbi.nlm.nih.gov/pubmed/21580532
http://dx.doi.org/10.1107/S1600536810009530
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AT xiaolingyun 14710tetraoxacyclododecanetrideuteroacetonitrilelithiumperchlorate
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