Sodium terbium(III) polyphosphate

Single crystals of the title compound, NaTb(PO(3))(4), were obtained by solid-state reaction. This compound belongs to type II of long-chain polyphosphates with the general formula A (I) B (III)(PO(3))(4). It is isotypic with the NaNd(PO(3))(4) and NaEr(PO(3))(4) homologues. The crystal structure is...

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Autores principales: Oudahmane, Abdelghani, Daoud, Mohamed, Tanouti, Boumediene, Avignant, Daniel, Zambon, Daniel
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983799/
https://www.ncbi.nlm.nih.gov/pubmed/21580462
http://dx.doi.org/10.1107/S1600536810010093
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author Oudahmane, Abdelghani
Daoud, Mohamed
Tanouti, Boumediene
Avignant, Daniel
Zambon, Daniel
author_facet Oudahmane, Abdelghani
Daoud, Mohamed
Tanouti, Boumediene
Avignant, Daniel
Zambon, Daniel
author_sort Oudahmane, Abdelghani
collection PubMed
description Single crystals of the title compound, NaTb(PO(3))(4), were obtained by solid-state reaction. This compound belongs to type II of long-chain polyphosphates with the general formula A (I) B (III)(PO(3))(4). It is isotypic with the NaNd(PO(3))(4) and NaEr(PO(3))(4) homologues. The crystal structure is built up of infinite crenelated chains of corner-sharing PO(4) tetra­hedra with a repeating unit of four tetra­hedra. These chains, extending parallel to [100], are linked by isolated TbO(8) square anti­prisms, forming a three-dimensional framework. The Na(+) ions are located in channels running along [010] and are surrounded by six oxygen atoms in a distorted octa­hedral environment within a cut-off distance <2.9 Å.
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spelling pubmed-29837992010-12-30 Sodium terbium(III) polyphosphate Oudahmane, Abdelghani Daoud, Mohamed Tanouti, Boumediene Avignant, Daniel Zambon, Daniel Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single crystals of the title compound, NaTb(PO(3))(4), were obtained by solid-state reaction. This compound belongs to type II of long-chain polyphosphates with the general formula A (I) B (III)(PO(3))(4). It is isotypic with the NaNd(PO(3))(4) and NaEr(PO(3))(4) homologues. The crystal structure is built up of infinite crenelated chains of corner-sharing PO(4) tetra­hedra with a repeating unit of four tetra­hedra. These chains, extending parallel to [100], are linked by isolated TbO(8) square anti­prisms, forming a three-dimensional framework. The Na(+) ions are located in channels running along [010] and are surrounded by six oxygen atoms in a distorted octa­hedral environment within a cut-off distance <2.9 Å. International Union of Crystallography 2010-03-24 /pmc/articles/PMC2983799/ /pubmed/21580462 http://dx.doi.org/10.1107/S1600536810010093 Text en © Oudahmane et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Oudahmane, Abdelghani
Daoud, Mohamed
Tanouti, Boumediene
Avignant, Daniel
Zambon, Daniel
Sodium terbium(III) polyphosphate
title Sodium terbium(III) polyphosphate
title_full Sodium terbium(III) polyphosphate
title_fullStr Sodium terbium(III) polyphosphate
title_full_unstemmed Sodium terbium(III) polyphosphate
title_short Sodium terbium(III) polyphosphate
title_sort sodium terbium(iii) polyphosphate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983799/
https://www.ncbi.nlm.nih.gov/pubmed/21580462
http://dx.doi.org/10.1107/S1600536810010093
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AT daoudmohamed sodiumterbiumiiipolyphosphate
AT tanoutiboumediene sodiumterbiumiiipolyphosphate
AT avignantdaniel sodiumterbiumiiipolyphosphate
AT zambondaniel sodiumterbiumiiipolyphosphate

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