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2,2′-[2,3,5,6-Tetramethyl-p-phenylenebis(methyleneoxy)]dibenzoic acid
The asymmetric unit of the title compound, C(26)H(26)O(6), contains only a half-molecule, the other half being generated by an inversion center. The two carboxyphenoxymethyl units occupy the 1,4-positions of the central aromatic ring. The central ring and the six linked C atoms are almost planar,...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983800/ https://www.ncbi.nlm.nih.gov/pubmed/21580791 http://dx.doi.org/10.1107/S1600536810011220 |
Sumario: | The asymmetric unit of the title compound, C(26)H(26)O(6), contains only a half-molecule, the other half being generated by an inversion center. The two carboxyphenoxymethyl units occupy the 1,4-positions of the central aromatic ring. The central ring and the six linked C atoms are almost planar, with a maximum deviation of 0.0286 (17) Å, and the plane makes a dihedral angle of 75.50 (6)° with the benzene ring. In the crystal, strong O—H⋯O hydrogen bonds between the carboxyl groups of adjacent molecules and C—H⋯π interactions link the molecules into zigzag chains along (220) and ([Image: see text]10); the two types of chain are arranged alternately, forming a three-dimensional framework. |
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