catena-Poly[[[triaqua­sulfatozinc(II)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate]

In the title coordination polymer, {[Zn(SO(4))(C(18)H(16)N(6)O(2))(H(2)O)(3)]·CH(3)OH·H(2)O}(n), the Zn(2+) ion adopts a slightly distorted cis-ZnN(2)O(4) octa­hedral geometry arising from three coordinated water mol­ecules, one sulfate ion and two bridging 3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)d...

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Detalles Bibliográficos
Autores principales: Adarsh, N. N., Dastidar, Parthasarathi
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983801/
https://www.ncbi.nlm.nih.gov/pubmed/21580512
http://dx.doi.org/10.1107/S1600536810009268
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author Adarsh, N. N.
Dastidar, Parthasarathi
author_facet Adarsh, N. N.
Dastidar, Parthasarathi
author_sort Adarsh, N. N.
collection PubMed
description In the title coordination polymer, {[Zn(SO(4))(C(18)H(16)N(6)O(2))(H(2)O)(3)]·CH(3)OH·H(2)O}(n), the Zn(2+) ion adopts a slightly distorted cis-ZnN(2)O(4) octa­hedral geometry arising from three coordinated water mol­ecules, one sulfate ion and two bridging 3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea (bpmpbu) ligands. The dihedral angles between the central benzene ring and two terminal pyridine rings of the bpmbpu mol­ecule are 10.58 (17) and 34.63 (16)°. In the crystal, the ligands bridge the Zn(II) ions, thus generating a one-dimensional zigzag coordination polymer propagating in [010]. The crystal structure features extensive N—H⋯O and O—H⋯O hydrogen-bonding inter­actions.
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spelling pubmed-29838012010-12-30 catena-Poly[[[triaqua­sulfatozinc(II)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate] Adarsh, N. N. Dastidar, Parthasarathi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, {[Zn(SO(4))(C(18)H(16)N(6)O(2))(H(2)O)(3)]·CH(3)OH·H(2)O}(n), the Zn(2+) ion adopts a slightly distorted cis-ZnN(2)O(4) octa­hedral geometry arising from three coordinated water mol­ecules, one sulfate ion and two bridging 3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea (bpmpbu) ligands. The dihedral angles between the central benzene ring and two terminal pyridine rings of the bpmbpu mol­ecule are 10.58 (17) and 34.63 (16)°. In the crystal, the ligands bridge the Zn(II) ions, thus generating a one-dimensional zigzag coordination polymer propagating in [010]. The crystal structure features extensive N—H⋯O and O—H⋯O hydrogen-bonding inter­actions. International Union of Crystallography 2010-03-17 /pmc/articles/PMC2983801/ /pubmed/21580512 http://dx.doi.org/10.1107/S1600536810009268 Text en © Adarsh and Dastidar 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Adarsh, N. N.
Dastidar, Parthasarathi
catena-Poly[[[triaqua­sulfatozinc(II)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate]
title catena-Poly[[[triaqua­sulfatozinc(II)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate]
title_full catena-Poly[[[triaqua­sulfatozinc(II)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate]
title_fullStr catena-Poly[[[triaqua­sulfatozinc(II)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate]
title_full_unstemmed catena-Poly[[[triaqua­sulfatozinc(II)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate]
title_short catena-Poly[[[triaqua­sulfatozinc(II)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate]
title_sort catena-poly[[[triaqua­sulfatozinc(ii)]-μ-3,3′-bis­(3-pyrid­yl)-1,1′-(m-phenyl­ene)diurea] methanol solvate monohydrate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983801/
https://www.ncbi.nlm.nih.gov/pubmed/21580512
http://dx.doi.org/10.1107/S1600536810009268
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