Hexaaqua­magnesium(II) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate]

In the title compound, [Mg(H(2)O)(6)](C(16)H(16)NO(5)S)(2), the Mg(2+) ion (site symmetry 2) adopts an almost regular octa­hedral coordination geometry. The anion is stabilized by an intra­molecular O—H⋯N hydrogen bond, generating an S(6) ring, and the dihedral angle between the aromatic rings is 41...

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Detalles Bibliográficos
Autores principales: Tai, Xi-Shi, Zhang, Fu-Gong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983805/
https://www.ncbi.nlm.nih.gov/pubmed/21580520
http://dx.doi.org/10.1107/S1600536810009748
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author Tai, Xi-Shi
Zhang, Fu-Gong
author_facet Tai, Xi-Shi
Zhang, Fu-Gong
author_sort Tai, Xi-Shi
collection PubMed
description In the title compound, [Mg(H(2)O)(6)](C(16)H(16)NO(5)S)(2), the Mg(2+) ion (site symmetry 2) adopts an almost regular octa­hedral coordination geometry. The anion is stabilized by an intra­molecular O—H⋯N hydrogen bond, generating an S(6) ring, and the dihedral angle between the aromatic rings is 41.02 (7)°. In the crystal, the cations and anions are linked by O—H⋯O hydrogen bonds, generating sheets lying parallel to (100).
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spelling pubmed-29838052010-12-30 Hexaaqua­magnesium(II) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate] Tai, Xi-Shi Zhang, Fu-Gong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Mg(H(2)O)(6)](C(16)H(16)NO(5)S)(2), the Mg(2+) ion (site symmetry 2) adopts an almost regular octa­hedral coordination geometry. The anion is stabilized by an intra­molecular O—H⋯N hydrogen bond, generating an S(6) ring, and the dihedral angle between the aromatic rings is 41.02 (7)°. In the crystal, the cations and anions are linked by O—H⋯O hydrogen bonds, generating sheets lying parallel to (100). International Union of Crystallography 2010-03-20 /pmc/articles/PMC2983805/ /pubmed/21580520 http://dx.doi.org/10.1107/S1600536810009748 Text en © Tai and Zhang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tai, Xi-Shi
Zhang, Fu-Gong
Hexaaqua­magnesium(II) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate]
title Hexaaqua­magnesium(II) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate]
title_full Hexaaqua­magnesium(II) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate]
title_fullStr Hexaaqua­magnesium(II) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate]
title_full_unstemmed Hexaaqua­magnesium(II) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate]
title_short Hexaaqua­magnesium(II) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate]
title_sort hexaaqua­magnesium(ii) bis­[4-(3-eth­oxy-2-hydroxy­benzyl­ideneamino)-3-methyl­benzene­sulfonate]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983805/
https://www.ncbi.nlm.nih.gov/pubmed/21580520
http://dx.doi.org/10.1107/S1600536810009748
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AT zhangfugong hexaaquamagnesiumiibis43ethoxy2hydroxybenzylideneamino3methylbenzenesulfonate

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