catena-Poly[[aqua­dioxidouranium(VI)]-μ(3)-4,4′-oxydibenzoato]

The title compound, [UO(2)(C(14)H(8)O(5))(H(2)O)](n), is a polymeric UO(2) complex bridged by 4,4′-oxydibenzoate ligands. One carboxyl­ate group of the bridging ligand chelates a uranyl cation while the other carboxyl­ate group of the ligand bridges two other two uranyl cations, forming a double-cha...

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Detalles Bibliográficos
Autores principales: Wang, Wei, Zhang, Dao-Jun, Fan, Yong, Song, Tian-You, Zhang, Ping
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983807/
https://www.ncbi.nlm.nih.gov/pubmed/21580547
http://dx.doi.org/10.1107/S1600536810010639
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author Wang, Wei
Zhang, Dao-Jun
Fan, Yong
Song, Tian-You
Zhang, Ping
author_facet Wang, Wei
Zhang, Dao-Jun
Fan, Yong
Song, Tian-You
Zhang, Ping
author_sort Wang, Wei
collection PubMed
description The title compound, [UO(2)(C(14)H(8)O(5))(H(2)O)](n), is a polymeric UO(2) complex bridged by 4,4′-oxydibenzoate ligands. One carboxyl­ate group of the bridging ligand chelates a uranyl cation while the other carboxyl­ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central U(VI) atom is seven-coordin­ated in a distorted UO(7) penta­gonal-bipyramidal geometry. In the crystal structure, O—H⋯O hydrogen bonding links the polymeric chains into a three-dimensional supra­molecular framework. Within the bridging ligand, the two benzene rings are oriented at a dihedral angle of 59.0 (2)°.
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spelling pubmed-29838072010-12-30 catena-Poly[[aqua­dioxidouranium(VI)]-μ(3)-4,4′-oxydibenzoato] Wang, Wei Zhang, Dao-Jun Fan, Yong Song, Tian-You Zhang, Ping Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [UO(2)(C(14)H(8)O(5))(H(2)O)](n), is a polymeric UO(2) complex bridged by 4,4′-oxydibenzoate ligands. One carboxyl­ate group of the bridging ligand chelates a uranyl cation while the other carboxyl­ate group of the ligand bridges two other two uranyl cations, forming a double-chain polymeric structure. The central U(VI) atom is seven-coordin­ated in a distorted UO(7) penta­gonal-bipyramidal geometry. In the crystal structure, O—H⋯O hydrogen bonding links the polymeric chains into a three-dimensional supra­molecular framework. Within the bridging ligand, the two benzene rings are oriented at a dihedral angle of 59.0 (2)°. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2983807/ /pubmed/21580547 http://dx.doi.org/10.1107/S1600536810010639 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Wei
Zhang, Dao-Jun
Fan, Yong
Song, Tian-You
Zhang, Ping
catena-Poly[[aqua­dioxidouranium(VI)]-μ(3)-4,4′-oxydibenzoato]
title catena-Poly[[aqua­dioxidouranium(VI)]-μ(3)-4,4′-oxydibenzoato]
title_full catena-Poly[[aqua­dioxidouranium(VI)]-μ(3)-4,4′-oxydibenzoato]
title_fullStr catena-Poly[[aqua­dioxidouranium(VI)]-μ(3)-4,4′-oxydibenzoato]
title_full_unstemmed catena-Poly[[aqua­dioxidouranium(VI)]-μ(3)-4,4′-oxydibenzoato]
title_short catena-Poly[[aqua­dioxidouranium(VI)]-μ(3)-4,4′-oxydibenzoato]
title_sort catena-poly[[aqua­dioxidouranium(vi)]-μ(3)-4,4′-oxydibenzoato]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983807/
https://www.ncbi.nlm.nih.gov/pubmed/21580547
http://dx.doi.org/10.1107/S1600536810010639
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AT songtianyou catenapolyaquadioxidouraniumvim344oxydibenzoato
AT zhangping catenapolyaquadioxidouraniumvim344oxydibenzoato

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