[(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph

The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P [Image: see text]) polymorph [Hall et al. (1993 ▶). Aust. J. Chem. 46, 561–570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that de...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983808/
https://www.ncbi.nlm.nih.gov/pubmed/21580504
http://dx.doi.org/10.1107/S1600536810009086
Descripción
Sumario:The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P [Image: see text]) polymorph [Hall et al. (1993 ▶). Aust. J. Chem. 46, 561–570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = = 175.43 (3)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.036 (2) Å]. In the crystal structure, mol­ecules are arranged into supra­molecular chains along the b axis mediated by C—H⋯π inter­actions.

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