[(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph

The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P [Image: see text]) polymorph [Hall et al. (1993 ▶). Aust. J. Chem. 46, 561–570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that de...

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Detalles Bibliográficos
Autores principales: Tadbuppa, Primjira P., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983808/
https://www.ncbi.nlm.nih.gov/pubmed/21580504
http://dx.doi.org/10.1107/S1600536810009086
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author Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_facet Tadbuppa, Primjira P.
Tiekink, Edward R. T.
author_sort Tadbuppa, Primjira P.
collection PubMed
description The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P [Image: see text]) polymorph [Hall et al. (1993 ▶). Aust. J. Chem. 46, 561–570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = = 175.43 (3)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.036 (2) Å]. In the crystal structure, mol­ecules are arranged into supra­molecular chains along the b axis mediated by C—H⋯π inter­actions.
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spelling pubmed-29838082010-12-30 [(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph Tadbuppa, Primjira P. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P [Image: see text]) polymorph [Hall et al. (1993 ▶). Aust. J. Chem. 46, 561–570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S—Au—P = = 175.43 (3)°], with the distortion due in part to a close intra­molecular Au⋯O contact [3.036 (2) Å]. In the crystal structure, mol­ecules are arranged into supra­molecular chains along the b axis mediated by C—H⋯π inter­actions. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2983808/ /pubmed/21580504 http://dx.doi.org/10.1107/S1600536810009086 Text en © Tadbuppa and Tiekink 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tadbuppa, Primjira P.
Tiekink, Edward R. T.
[(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph
title [(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph
title_full [(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph
title_fullStr [(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph
title_full_unstemmed [(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph
title_short [(Z)-O-Ethyl N-phenyl­thio­carbamato-κS](tricyclo­hexyl­phosphine-κP)gold(I): a monoclinic polymorph
title_sort [(z)-o-ethyl n-phenyl­thio­carbamato-κs](tricyclo­hexyl­phosphine-κp)gold(i): a monoclinic polymorph
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983808/
https://www.ncbi.nlm.nih.gov/pubmed/21580504
http://dx.doi.org/10.1107/S1600536810009086
work_keys_str_mv AT tadbuppaprimjirap zoethylnphenylthiocarbamatokstricyclohexylphosphinekpgoldiamonoclinicpolymorph
AT tiekinkedwardrt zoethylnphenylthiocarbamatokstricyclohexylphosphinekpgoldiamonoclinicpolymorph

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