Dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(II) hemihydrate

The title Cu(II) complex, [CuBr(2)(C(21)H(15)N(3))]·0.5H(2)O, was obtained by the hydro­thermal reaction of copper(II) bromide, 4′-phenyl-2,2′:6′,2′′-terpyridyl (4′-Ph-terpy or L) and sodium citrate in water in 31% yield. There are two unique complex mol­ecules and a water mol­ecule in the asymmetri...

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Autores principales: Ma, Zhen, Bi, Chunyan, Ran, Guangyou, Wu, Zhang, Liu, Baoqing, Hu, Miao, Xing, Yanpeng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983813/
https://www.ncbi.nlm.nih.gov/pubmed/21580549
http://dx.doi.org/10.1107/S1600536810010585
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author Ma, Zhen
Bi, Chunyan
Ran, Guangyou
Wu, Zhang
Liu, Baoqing
Hu, Miao
Xing, Yanpeng
author_facet Ma, Zhen
Bi, Chunyan
Ran, Guangyou
Wu, Zhang
Liu, Baoqing
Hu, Miao
Xing, Yanpeng
author_sort Ma, Zhen
collection PubMed
description The title Cu(II) complex, [CuBr(2)(C(21)H(15)N(3))]·0.5H(2)O, was obtained by the hydro­thermal reaction of copper(II) bromide, 4′-phenyl-2,2′:6′,2′′-terpyridyl (4′-Ph-terpy or L) and sodium citrate in water in 31% yield. There are two unique complex mol­ecules and a water mol­ecule in the asymmetric unit. The Cu(II) cation is ligated by three N atoms of L and two bromide anions, forming an irregular CuN(3)Br(2) polyhedron with a distorted square-pyramidal coordination geometry. In the crystal structure, O—H⋯Br hydrogen bonds link the mol­ecules in a three-dimensional network.
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spelling pubmed-29838132010-12-30 Dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(II) hemihydrate Ma, Zhen Bi, Chunyan Ran, Guangyou Wu, Zhang Liu, Baoqing Hu, Miao Xing, Yanpeng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title Cu(II) complex, [CuBr(2)(C(21)H(15)N(3))]·0.5H(2)O, was obtained by the hydro­thermal reaction of copper(II) bromide, 4′-phenyl-2,2′:6′,2′′-terpyridyl (4′-Ph-terpy or L) and sodium citrate in water in 31% yield. There are two unique complex mol­ecules and a water mol­ecule in the asymmetric unit. The Cu(II) cation is ligated by three N atoms of L and two bromide anions, forming an irregular CuN(3)Br(2) polyhedron with a distorted square-pyramidal coordination geometry. In the crystal structure, O—H⋯Br hydrogen bonds link the mol­ecules in a three-dimensional network. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2983813/ /pubmed/21580549 http://dx.doi.org/10.1107/S1600536810010585 Text en © Ma et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Ma, Zhen
Bi, Chunyan
Ran, Guangyou
Wu, Zhang
Liu, Baoqing
Hu, Miao
Xing, Yanpeng
Dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(II) hemihydrate
title Dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(II) hemihydrate
title_full Dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(II) hemihydrate
title_fullStr Dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(II) hemihydrate
title_full_unstemmed Dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(II) hemihydrate
title_short Dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(II) hemihydrate
title_sort dibrom­ido(4′-phenyl-2,2′:6′,2′′-terpyrid­yl)copper(ii) hemihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983813/
https://www.ncbi.nlm.nih.gov/pubmed/21580549
http://dx.doi.org/10.1107/S1600536810010585
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AT wuzhang dibromido4phenyl2262terpyridylcopperiihemihydrate
AT liubaoqing dibromido4phenyl2262terpyridylcopperiihemihydrate
AT humiao dibromido4phenyl2262terpyridylcopperiihemihydrate
AT xingyanpeng dibromido4phenyl2262terpyridylcopperiihemihydrate

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