Di-μ-sulfato-κ(4) O:O′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(II)}

In the centrosymmetric binuclear title molecule, [Co(2)(SO(4))(2)(C(8)H(7)N(3))(4)], the Co(II) ion is coordinated by two N,N′-bidentate 3-(2-pyrid­yl)pyrazole ligands and two sulfate ions, generating a distorted cis-CoO(2)N(4) octa­hedral geometry for the metal atom. The dihedral angles between the...

Descripción completa

Detalles Bibliográficos
Autores principales: Lin, Pei-Xi, Yang, Gui-Bin, An, Zhe
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983814/
https://www.ncbi.nlm.nih.gov/pubmed/21580486
http://dx.doi.org/10.1107/S160053681000797X
_version_ 1782191964512321536
author Lin, Pei-Xi
Yang, Gui-Bin
An, Zhe
author_facet Lin, Pei-Xi
Yang, Gui-Bin
An, Zhe
author_sort Lin, Pei-Xi
collection PubMed
description In the centrosymmetric binuclear title molecule, [Co(2)(SO(4))(2)(C(8)H(7)N(3))(4)], the Co(II) ion is coordinated by two N,N′-bidentate 3-(2-pyrid­yl)pyrazole ligands and two sulfate ions, generating a distorted cis-CoO(2)N(4) octa­hedral geometry for the metal atom. The dihedral angles between the pyridine and pyrazole rings in the two ligands are 10.5 (2) and 7.38 (19)°. The bridging sulfate ions generate an eight-membered ring and intra­molecular N—H⋯O hydrogen bonds help to establish the mol­ecular conformation.
format Text
id pubmed-2983814
institution National Center for Biotechnology Information
language English
publishDate 2010
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-29838142010-12-30 Di-μ-sulfato-κ(4) O:O′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(II)} Lin, Pei-Xi Yang, Gui-Bin An, Zhe Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric binuclear title molecule, [Co(2)(SO(4))(2)(C(8)H(7)N(3))(4)], the Co(II) ion is coordinated by two N,N′-bidentate 3-(2-pyrid­yl)pyrazole ligands and two sulfate ions, generating a distorted cis-CoO(2)N(4) octa­hedral geometry for the metal atom. The dihedral angles between the pyridine and pyrazole rings in the two ligands are 10.5 (2) and 7.38 (19)°. The bridging sulfate ions generate an eight-membered ring and intra­molecular N—H⋯O hydrogen bonds help to establish the mol­ecular conformation. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983814/ /pubmed/21580486 http://dx.doi.org/10.1107/S160053681000797X Text en © Lin et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Lin, Pei-Xi
Yang, Gui-Bin
An, Zhe
Di-μ-sulfato-κ(4) O:O′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(II)}
title Di-μ-sulfato-κ(4) O:O′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(II)}
title_full Di-μ-sulfato-κ(4) O:O′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(II)}
title_fullStr Di-μ-sulfato-κ(4) O:O′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(II)}
title_full_unstemmed Di-μ-sulfato-κ(4) O:O′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(II)}
title_short Di-μ-sulfato-κ(4) O:O′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(II)}
title_sort di-μ-sulfato-κ(4) o:o′-bis­{bis­[3-(2-pyrid­yl)pyrazole]cobalt(ii)}
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983814/
https://www.ncbi.nlm.nih.gov/pubmed/21580486
http://dx.doi.org/10.1107/S160053681000797X
work_keys_str_mv AT linpeixi dimsulfatok4oobisbis32pyridylpyrazolecobaltii
AT yangguibin dimsulfatok4oobisbis32pyridylpyrazolecobaltii
AT anzhe dimsulfatok4oobisbis32pyridylpyrazolecobaltii

Ejemplares similares