Hexakis(tetra­aqua­sodium) deca­vanadate(V) dihydrate

The title compound, {[Na(H(2)O)(4)](6)[V(10)O(28)]·2H(2)O}(n), crystallized from a H(2)O/THF/CH(3)CN solution (pH ca 6) containing equimolar amounts of NaVO(3) and N-(2-hydroxy­benz­yl)-N-(2-picol­yl)glycine. In the crystal structure, the deca­vanadate [V(10)O(28)](6−) anion ([Image: see text] symme...

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Autores principales: Nilsson, Jessica, Nordlander, Ebbe, Behrens, Ulrich, Rehder, Dieter
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983821/
https://www.ncbi.nlm.nih.gov/pubmed/21580463
http://dx.doi.org/10.1107/S1600536810010251
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author Nilsson, Jessica
Nordlander, Ebbe
Behrens, Ulrich
Rehder, Dieter
author_facet Nilsson, Jessica
Nordlander, Ebbe
Behrens, Ulrich
Rehder, Dieter
author_sort Nilsson, Jessica
collection PubMed
description The title compound, {[Na(H(2)O)(4)](6)[V(10)O(28)]·2H(2)O}(n), crystallized from a H(2)O/THF/CH(3)CN solution (pH ca 6) containing equimolar amounts of NaVO(3) and N-(2-hydroxy­benz­yl)-N-(2-picol­yl)glycine. In the crystal structure, the deca­vanadate [V(10)O(28)](6−) anion ([Image: see text] symmetry) is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H(2)O)(3)}(2)(μ-H(2)O)(2)](2+) units. Inter­connection of these aquasodium-ion-sandwiched deca­vanadates to chains parallel to [001] is effected by μ-[{Na(H(2)O)(3)}(2)(μ-H(2)O)(2)](2+) units, bridging adjacent deca­vanadates via O=V. The structure is consolidated by an extensive network of O—H⋯O hydrogen bonds.
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spelling pubmed-29838212010-12-30 Hexakis(tetra­aqua­sodium) deca­vanadate(V) dihydrate Nilsson, Jessica Nordlander, Ebbe Behrens, Ulrich Rehder, Dieter Acta Crystallogr Sect E Struct Rep Online Inorganic Papers The title compound, {[Na(H(2)O)(4)](6)[V(10)O(28)]·2H(2)O}(n), crystallized from a H(2)O/THF/CH(3)CN solution (pH ca 6) containing equimolar amounts of NaVO(3) and N-(2-hydroxy­benz­yl)-N-(2-picol­yl)glycine. In the crystal structure, the deca­vanadate [V(10)O(28)](6−) anion ([Image: see text] symmetry) is coordinated, via four terminal oxide ligands of V centres, to two dinuclear [{Na(H(2)O)(3)}(2)(μ-H(2)O)(2)](2+) units. Inter­connection of these aquasodium-ion-sandwiched deca­vanadates to chains parallel to [001] is effected by μ-[{Na(H(2)O)(3)}(2)(μ-H(2)O)(2)](2+) units, bridging adjacent deca­vanadates via O=V. The structure is consolidated by an extensive network of O—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-24 /pmc/articles/PMC2983821/ /pubmed/21580463 http://dx.doi.org/10.1107/S1600536810010251 Text en © Nilsson et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Nilsson, Jessica
Nordlander, Ebbe
Behrens, Ulrich
Rehder, Dieter
Hexakis(tetra­aqua­sodium) deca­vanadate(V) dihydrate
title Hexakis(tetra­aqua­sodium) deca­vanadate(V) dihydrate
title_full Hexakis(tetra­aqua­sodium) deca­vanadate(V) dihydrate
title_fullStr Hexakis(tetra­aqua­sodium) deca­vanadate(V) dihydrate
title_full_unstemmed Hexakis(tetra­aqua­sodium) deca­vanadate(V) dihydrate
title_short Hexakis(tetra­aqua­sodium) deca­vanadate(V) dihydrate
title_sort hexakis(tetra­aqua­sodium) deca­vanadate(v) dihydrate
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983821/
https://www.ncbi.nlm.nih.gov/pubmed/21580463
http://dx.doi.org/10.1107/S1600536810010251
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AT nordlanderebbe hexakistetraaquasodiumdecavanadatevdihydrate
AT behrensulrich hexakistetraaquasodiumdecavanadatevdihydrate
AT rehderdieter hexakistetraaquasodiumdecavanadatevdihydrate

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