{1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II)

In the title Schiff base complex, [Ni(C(27)H(24)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the two aromatic rings is 6.16 (6)°. In the crystal, pairs of inter­molecular weak C—H⋯O hydrogen bonds link neighboring mol­ec...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Khan, Islam Ullah, Zare, Karim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983828/
https://www.ncbi.nlm.nih.gov/pubmed/21580475
http://dx.doi.org/10.1107/S1600536810007373
Descripción
Sumario:In the title Schiff base complex, [Ni(C(27)H(24)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the two aromatic rings is 6.16 (6)°. In the crystal, pairs of inter­molecular weak C—H⋯O hydrogen bonds link neighboring mol­ecules into a chain along the a axis. The crystal structure is further stabilized by two inter­molecular π–π inter­actions with centroid–centroid distances of 3.7252 (13) and 3.8323 (13) Å.

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