{1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II)

In the title Schiff base complex, [Ni(C(27)H(24)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the two aromatic rings is 6.16 (6)°. In the crystal, pairs of inter­molecular weak C—H⋯O hydrogen bonds link neighboring mol­ec...

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Detalles Bibliográficos
Autores principales: Kargar, Hadi, Kia, Reza, Khan, Islam Ullah, Zare, Karim
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983828/
https://www.ncbi.nlm.nih.gov/pubmed/21580475
http://dx.doi.org/10.1107/S1600536810007373
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author Kargar, Hadi
Kia, Reza
Khan, Islam Ullah
Zare, Karim
author_facet Kargar, Hadi
Kia, Reza
Khan, Islam Ullah
Zare, Karim
author_sort Kargar, Hadi
collection PubMed
description In the title Schiff base complex, [Ni(C(27)H(24)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the two aromatic rings is 6.16 (6)°. In the crystal, pairs of inter­molecular weak C—H⋯O hydrogen bonds link neighboring mol­ecules into a chain along the a axis. The crystal structure is further stabilized by two inter­molecular π–π inter­actions with centroid–centroid distances of 3.7252 (13) and 3.8323 (13) Å.
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spelling pubmed-29838282010-12-30 {1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II) Kargar, Hadi Kia, Reza Khan, Islam Ullah Zare, Karim Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title Schiff base complex, [Ni(C(27)H(24)N(2)O(2))], the Ni(II) atom shows a slightly distorted square-planar geometry. The dihedral angle between the mean planes of the two aromatic rings is 6.16 (6)°. In the crystal, pairs of inter­molecular weak C—H⋯O hydrogen bonds link neighboring mol­ecules into a chain along the a axis. The crystal structure is further stabilized by two inter­molecular π–π inter­actions with centroid–centroid distances of 3.7252 (13) and 3.8323 (13) Å. International Union of Crystallography 2010-03-03 /pmc/articles/PMC2983828/ /pubmed/21580475 http://dx.doi.org/10.1107/S1600536810007373 Text en © Kargar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Kargar, Hadi
Kia, Reza
Khan, Islam Ullah
Zare, Karim
{1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II)
title {1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II)
title_full {1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II)
title_fullStr {1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II)
title_full_unstemmed {1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II)
title_short {1,1′-[2,2-Dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(II)
title_sort {1,1′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]di-2-naphtholato}nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983828/
https://www.ncbi.nlm.nih.gov/pubmed/21580475
http://dx.doi.org/10.1107/S1600536810007373
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AT zarekarim 1122dimethylpropane13diylbisnitrilomethylidynedi2naphtholatonickelii

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