Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV)

The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(2)H(3)O(2))(2)(C(5)H(5)N)], contains two crystallography independent mol­ecules. In both mol­ecules, the Sn(IV) atom is seven-coordinated in a distorted penta­gonal-bipyramidal geometry with the two phenyl groups in axial positions. The t...

Descripción completa

Detalles Bibliográficos
Autores principales: Khaledi, Hamid, Mohd Ali, Hapipah, Abdulla, Mahmood A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983829/
https://www.ncbi.nlm.nih.gov/pubmed/21580466
http://dx.doi.org/10.1107/S1600536810007014
Descripción
Sumario:The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(2)H(3)O(2))(2)(C(5)H(5)N)], contains two crystallography independent mol­ecules. In both mol­ecules, the Sn(IV) atom is seven-coordinated in a distorted penta­gonal-bipyramidal geometry with the two phenyl groups in axial positions. The two mol­ecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15) and 60.11 (14)° in the two mol­ecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2) and 41.77 (13)° in the two mol­ecules.

Ejemplares similares