Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV)

The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(2)H(3)O(2))(2)(C(5)H(5)N)], contains two crystallography independent mol­ecules. In both mol­ecules, the Sn(IV) atom is seven-coordinated in a distorted penta­gonal-bipyramidal geometry with the two phenyl groups in axial positions. The t...

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Detalles Bibliográficos
Autores principales: Khaledi, Hamid, Mohd Ali, Hapipah, Abdulla, Mahmood A.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983829/
https://www.ncbi.nlm.nih.gov/pubmed/21580466
http://dx.doi.org/10.1107/S1600536810007014
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author Khaledi, Hamid
Mohd Ali, Hapipah
Abdulla, Mahmood A.
author_facet Khaledi, Hamid
Mohd Ali, Hapipah
Abdulla, Mahmood A.
author_sort Khaledi, Hamid
collection PubMed
description The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(2)H(3)O(2))(2)(C(5)H(5)N)], contains two crystallography independent mol­ecules. In both mol­ecules, the Sn(IV) atom is seven-coordinated in a distorted penta­gonal-bipyramidal geometry with the two phenyl groups in axial positions. The two mol­ecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15) and 60.11 (14)° in the two mol­ecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2) and 41.77 (13)° in the two mol­ecules.
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spelling pubmed-29838292010-12-30 Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV) Khaledi, Hamid Mohd Ali, Hapipah Abdulla, Mahmood A. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The asymmetric unit of the title compound, [Sn(C(6)H(5))(2)(C(2)H(3)O(2))(2)(C(5)H(5)N)], contains two crystallography independent mol­ecules. In both mol­ecules, the Sn(IV) atom is seven-coordinated in a distorted penta­gonal-bipyramidal geometry with the two phenyl groups in axial positions. The two mol­ecules differ mainly in the torsion of the phenyl and pyridine rings. The dihredral angles between the phenyl rings are 89.54 (15) and 60.11 (14)° in the two mol­ecules while the dihedral angles between the pyridine rings and the acetate groups are 12.6 (2) and 41.77 (13)° in the two mol­ecules. International Union of Crystallography 2010-03-03 /pmc/articles/PMC2983829/ /pubmed/21580466 http://dx.doi.org/10.1107/S1600536810007014 Text en © Khaledi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Khaledi, Hamid
Mohd Ali, Hapipah
Abdulla, Mahmood A.
Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV)
title Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV)
title_full Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV)
title_fullStr Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV)
title_full_unstemmed Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV)
title_short Bis(acetato-κ(2) O,O′)diphen­yl(pyridine-κN)tin(IV)
title_sort bis(acetato-κ(2) o,o′)diphen­yl(pyridine-κn)tin(iv)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983829/
https://www.ncbi.nlm.nih.gov/pubmed/21580466
http://dx.doi.org/10.1107/S1600536810007014
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AT mohdalihapipah bisacetatok2oodiphenylpyridinekntiniv
AT abdullamahmooda bisacetatok2oodiphenylpyridinekntiniv

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