Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I)

The title compound, (C(12)H(28)N)(2)[Cu(3.194)I(6)(C(5)H(5)N)(2)] was prepared from reaction of copper powder, copper(I) oxide, hydro­iodic acid, tetra­propyl­ammonium iodide and pyridine under hydro­thermal conditions. In the centrosymmetric Cu(4)I(6) (2−) anion, one Cu site is in a trigonal-planar...

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Detalles Bibliográficos
Autor principal: Jalilian, Ehsan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983839/
https://www.ncbi.nlm.nih.gov/pubmed/21580527
http://dx.doi.org/10.1107/S1600536810010202
Descripción
Sumario:The title compound, (C(12)H(28)N)(2)[Cu(3.194)I(6)(C(5)H(5)N)(2)] was prepared from reaction of copper powder, copper(I) oxide, hydro­iodic acid, tetra­propyl­ammonium iodide and pyridine under hydro­thermal conditions. In the centrosymmetric Cu(4)I(6) (2−) anion, one Cu site is in a trigonal-planar coordination while the second Cu site, which is only partially occupied [site occupancy of 0.5968 (16)], is surroundedby three iodine atoms and one pyridine molecule in a distorted tetrahedral coordination.

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