Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I)

The title compound, (C(12)H(28)N)(2)[Cu(3.194)I(6)(C(5)H(5)N)(2)] was prepared from reaction of copper powder, copper(I) oxide, hydro­iodic acid, tetra­propyl­ammonium iodide and pyridine under hydro­thermal conditions. In the centrosymmetric Cu(4)I(6) (2−) anion, one Cu site is in a trigonal-planar...

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Detalles Bibliográficos
Autor principal: Jalilian, Ehsan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983839/
https://www.ncbi.nlm.nih.gov/pubmed/21580527
http://dx.doi.org/10.1107/S1600536810010202
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author Jalilian, Ehsan
author_facet Jalilian, Ehsan
author_sort Jalilian, Ehsan
collection PubMed
description The title compound, (C(12)H(28)N)(2)[Cu(3.194)I(6)(C(5)H(5)N)(2)] was prepared from reaction of copper powder, copper(I) oxide, hydro­iodic acid, tetra­propyl­ammonium iodide and pyridine under hydro­thermal conditions. In the centrosymmetric Cu(4)I(6) (2−) anion, one Cu site is in a trigonal-planar coordination while the second Cu site, which is only partially occupied [site occupancy of 0.5968 (16)], is surroundedby three iodine atoms and one pyridine molecule in a distorted tetrahedral coordination.
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spelling pubmed-29838392010-12-30 Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I) Jalilian, Ehsan Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(12)H(28)N)(2)[Cu(3.194)I(6)(C(5)H(5)N)(2)] was prepared from reaction of copper powder, copper(I) oxide, hydro­iodic acid, tetra­propyl­ammonium iodide and pyridine under hydro­thermal conditions. In the centrosymmetric Cu(4)I(6) (2−) anion, one Cu site is in a trigonal-planar coordination while the second Cu site, which is only partially occupied [site occupancy of 0.5968 (16)], is surroundedby three iodine atoms and one pyridine molecule in a distorted tetrahedral coordination. International Union of Crystallography 2010-03-24 /pmc/articles/PMC2983839/ /pubmed/21580527 http://dx.doi.org/10.1107/S1600536810010202 Text en © Ehsan Jalilian 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Jalilian, Ehsan
Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I)
title Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I)
title_full Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I)
title_fullStr Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I)
title_full_unstemmed Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I)
title_short Bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(I)
title_sort bis(tetra­propyl­ammonium) di-μ(3)-iodido-di-μ(2)-iodido-diiodidodi­pyridine­tetra­copper(i)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983839/
https://www.ncbi.nlm.nih.gov/pubmed/21580527
http://dx.doi.org/10.1107/S1600536810010202
work_keys_str_mv AT jalilianehsan bistetrapropylammoniumdim3iodidodim2iodidodiiodidodipyridinetetracopperi

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