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{6,6′-Diethoxy-2,2′-[2,2-dimethylpropane-1,3-diylbis(nitrilomethylidyne)]diphenolato}(2-ethoxy-6-formylphenolato)cobalt(III)–ethanol–water (1/1/1)
The asymmetric unit of the title compound, [Co(C(23)H(28)N(2)O(4))(C(9)H(9)O(3))]·C(2)H(5)OH·H(2)O, comprises one complex molecule, a water molecule of crystallization and an ethanol molecule of crystallization, which is disordered over two positions with a ratio of refined site occupancies of 0....
Autores principales: | , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983841/ https://www.ncbi.nlm.nih.gov/pubmed/21580480 http://dx.doi.org/10.1107/S1600536810007622 |
Sumario: | The asymmetric unit of the title compound, [Co(C(23)H(28)N(2)O(4))(C(9)H(9)O(3))]·C(2)H(5)OH·H(2)O, comprises one complex molecule, a water molecule of crystallization and an ethanol molecule of crystallization, which is disordered over two positions with a ratio of refined site occupancies of 0.567 (10):0.433 (10). The Co(III) ion is in a slightly distorted octahedral geometry involving an N(2)O(2) atom set of the tetradenate Schiff base ligand and two O atoms of 2-ethoxy-6-formylphenolate. The H atoms of the water molecule act as donors in the formation of bifurcated intermolecular O—H⋯(O,O) hydrogen bonds with the O atoms of the hydroxy and ethoxy groups with R (1) (2)(5) ring motifs, which may influence the molecular conformation. The crystal structure is further stabilized by intermolecular O—H⋯O and C—H⋯O interactions. |
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