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{6,6′-Dieth­oxy-2,2′-[2,2-dimethyl­propane-1,3-diylbis(nitrilo­methyl­idyne)]diphenolato}(2-eth­oxy-6-formyl­phenolato)cobalt(III)–ethanol–water (1/1/1)

The asymmetric unit of the title compound, [Co(C(23)H(28)N(2)O(4))(C(9)H(9)O(3))]·C(2)H(5)OH·H(2)O, comprises one complex mol­ecule, a water mol­ecule of crystallization and an ethanol mol­ecule of crystallization, which is disordered over two positions with a ratio of refined site occupancies of 0....

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Detalles Bibliográficos
Autores principales: Kia, Reza, Kargar, Hadi, Zare, Karim, Khan, Islam Ullah
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983841/
https://www.ncbi.nlm.nih.gov/pubmed/21580480
http://dx.doi.org/10.1107/S1600536810007622
Descripción
Sumario:The asymmetric unit of the title compound, [Co(C(23)H(28)N(2)O(4))(C(9)H(9)O(3))]·C(2)H(5)OH·H(2)O, comprises one complex mol­ecule, a water mol­ecule of crystallization and an ethanol mol­ecule of crystallization, which is disordered over two positions with a ratio of refined site occupancies of 0.567 (10):0.433 (10). The Co(III) ion is in a slightly distorted octa­hedral geometry involving an N(2)O(2) atom set of the tetra­denate Schiff base ligand and two O atoms of 2-eth­oxy-6-formyl­phenolate. The H atoms of the water mol­ecule act as donors in the formation of bifurcated inter­molecular O—H⋯(O,O) hydrogen bonds with the O atoms of the hydr­oxy and eth­oxy groups with R (1) (2)(5) ring motifs, which may influence the mol­ecular conformation. The crystal structure is further stabilized by inter­molecular O—H⋯O and C—H⋯O inter­actions.