Cargando…
Benzene-1,3,5-triyl tris(methanesulfonate)
In the molecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C—O—S angle range is 119.3 (2)–121.1 (2)°. This conformation is different from that of the benzene analog 1,2,5-tris(p-toluenesulfonate), which is a thr...
Autores principales: | , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983843/ https://www.ncbi.nlm.nih.gov/pubmed/21580584 http://dx.doi.org/10.1107/S1600536810006641 |
Sumario: | In the molecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C—O—S angle range is 119.3 (2)–121.1 (2)°. This conformation is different from that of the benzene analog 1,2,5-tris(p-toluenesulfonate), which is a three-legged ‘table’ with all fragments of the p-toluenesulfonate on top of the benzene ring. In the crystal, the supramolecular aggregation is completed by the presence of C—H⋯O hydrogen bonds. |
---|