Benzene-1,3,5-triyl tris­(methane­sulfonate)

In the mol­ecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C—O—S angle range is 119.3 (2)–121.1 (2)°. This conformation is different from that of the benzene analog 1,2,5-tris­(p-toluene­sulfonate), which is a thr...

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Detalles Bibliográficos
Autores principales: Madrigal, Domingo, Aguirre, Gerardo, Vargas, Berenice
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983843/
https://www.ncbi.nlm.nih.gov/pubmed/21580584
http://dx.doi.org/10.1107/S1600536810006641
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author Madrigal, Domingo
Aguirre, Gerardo
Vargas, Berenice
author_facet Madrigal, Domingo
Aguirre, Gerardo
Vargas, Berenice
author_sort Madrigal, Domingo
collection PubMed
description In the mol­ecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C—O—S angle range is 119.3 (2)–121.1 (2)°. This conformation is different from that of the benzene analog 1,2,5-tris­(p-toluene­sulfonate), which is a three-legged ‘table’ with all fragments of the p-toluene­sulfonate on top of the benzene ring. In the crystal, the supra­molecular aggregation is completed by the presence of C—H⋯O hydrogen bonds.
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spelling pubmed-29838432010-12-30 Benzene-1,3,5-triyl tris­(methane­sulfonate) Madrigal, Domingo Aguirre, Gerardo Vargas, Berenice Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecule of the title compound, C(9)H(12)O(9)S(3), the two methanesulfonate groups re located one above and one below the ring plane. The C—O—S angle range is 119.3 (2)–121.1 (2)°. This conformation is different from that of the benzene analog 1,2,5-tris­(p-toluene­sulfonate), which is a three-legged ‘table’ with all fragments of the p-toluene­sulfonate on top of the benzene ring. In the crystal, the supra­molecular aggregation is completed by the presence of C—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-03 /pmc/articles/PMC2983843/ /pubmed/21580584 http://dx.doi.org/10.1107/S1600536810006641 Text en © Madrigal et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Madrigal, Domingo
Aguirre, Gerardo
Vargas, Berenice
Benzene-1,3,5-triyl tris­(methane­sulfonate)
title Benzene-1,3,5-triyl tris­(methane­sulfonate)
title_full Benzene-1,3,5-triyl tris­(methane­sulfonate)
title_fullStr Benzene-1,3,5-triyl tris­(methane­sulfonate)
title_full_unstemmed Benzene-1,3,5-triyl tris­(methane­sulfonate)
title_short Benzene-1,3,5-triyl tris­(methane­sulfonate)
title_sort benzene-1,3,5-triyl tris­(methane­sulfonate)
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983843/
https://www.ncbi.nlm.nih.gov/pubmed/21580584
http://dx.doi.org/10.1107/S1600536810006641
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AT aguirregerardo benzene135triyltrismethanesulfonate
AT vargasberenice benzene135triyltrismethanesulfonate

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