3-Chloro-N-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide

In the mol­ecular structure of the title compound, C(13)H(18)ClNO(3), the amide group is nearly perpendicular to the benzene ring, making a dihedral angle of 85.66 (9)°. The C=O bond distance of 1.242 (3) Å and the C—N bond distance of 1.333 (3) Å suggest electron delocalization in the amide fragmen...

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Detalles Bibliográficos
Autores principales: Huang, Yan-Lan, Wang, Wen-Long, Shan, Shang
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983855/
https://www.ncbi.nlm.nih.gov/pubmed/21580696
http://dx.doi.org/10.1107/S1600536810009529
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author Huang, Yan-Lan
Wang, Wen-Long
Shan, Shang
author_facet Huang, Yan-Lan
Wang, Wen-Long
Shan, Shang
author_sort Huang, Yan-Lan
collection PubMed
description In the mol­ecular structure of the title compound, C(13)H(18)ClNO(3), the amide group is nearly perpendicular to the benzene ring, making a dihedral angle of 85.66 (9)°. The C=O bond distance of 1.242 (3) Å and the C—N bond distance of 1.333 (3) Å suggest electron delocalization in the amide fragment. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonding helps to stabilize the crystal structure.
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spelling pubmed-29838552010-12-30 3-Chloro-N-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide Huang, Yan-Lan Wang, Wen-Long Shan, Shang Acta Crystallogr Sect E Struct Rep Online Organic Papers In the mol­ecular structure of the title compound, C(13)H(18)ClNO(3), the amide group is nearly perpendicular to the benzene ring, making a dihedral angle of 85.66 (9)°. The C=O bond distance of 1.242 (3) Å and the C—N bond distance of 1.333 (3) Å suggest electron delocalization in the amide fragment. Inter­molecular O—H⋯O and N—H⋯O hydrogen bonding helps to stabilize the crystal structure. International Union of Crystallography 2010-03-20 /pmc/articles/PMC2983855/ /pubmed/21580696 http://dx.doi.org/10.1107/S1600536810009529 Text en © Huang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Huang, Yan-Lan
Wang, Wen-Long
Shan, Shang
3-Chloro-N-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide
title 3-Chloro-N-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide
title_full 3-Chloro-N-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide
title_fullStr 3-Chloro-N-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide
title_full_unstemmed 3-Chloro-N-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide
title_short 3-Chloro-N-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide
title_sort 3-chloro-n-(4-hydr­oxy-3-methoxy­benz­yl)-2,2-dimethyl­propanamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983855/
https://www.ncbi.nlm.nih.gov/pubmed/21580696
http://dx.doi.org/10.1107/S1600536810009529
work_keys_str_mv AT huangyanlan 3chloron4hydroxy3methoxybenzyl22dimethylpropanamide
AT wangwenlong 3chloron4hydroxy3methoxybenzyl22dimethylpropanamide
AT shanshang 3chloron4hydroxy3methoxybenzyl22dimethylpropanamide

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