N′-(5-Bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide

The title Schiff base, C(14)H(10)BrClN(2)O(2), exists in a trans configuration with respect to the C=N bond and the dihedral angle between the two benzene rings is 0.8 (2)°. There is an intra­molecular O—H⋯N hydrogen bond in the mol­ecule, which generates an S(6) loop. In the crystal, inter­molecula...

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Detalles Bibliográficos
Autores principales: Zhou, Cong-Shan, Yang, Tao
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983862/
https://www.ncbi.nlm.nih.gov/pubmed/21580596
http://dx.doi.org/10.1107/S160053681000752X
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author Zhou, Cong-Shan
Yang, Tao
author_facet Zhou, Cong-Shan
Yang, Tao
author_sort Zhou, Cong-Shan
collection PubMed
description The title Schiff base, C(14)H(10)BrClN(2)O(2), exists in a trans configuration with respect to the C=N bond and the dihedral angle between the two benzene rings is 0.8 (2)°. There is an intra­molecular O—H⋯N hydrogen bond in the mol­ecule, which generates an S(6) loop. In the crystal, inter­molecular N—H⋯O hydrogen bonds link adjacent mol­ecules into extended chains propagating along the c-axis direction.
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spelling pubmed-29838622010-12-30 N′-(5-Bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide Zhou, Cong-Shan Yang, Tao Acta Crystallogr Sect E Struct Rep Online Organic Papers The title Schiff base, C(14)H(10)BrClN(2)O(2), exists in a trans configuration with respect to the C=N bond and the dihedral angle between the two benzene rings is 0.8 (2)°. There is an intra­molecular O—H⋯N hydrogen bond in the mol­ecule, which generates an S(6) loop. In the crystal, inter­molecular N—H⋯O hydrogen bonds link adjacent mol­ecules into extended chains propagating along the c-axis direction. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983862/ /pubmed/21580596 http://dx.doi.org/10.1107/S160053681000752X Text en © Zhou and Yang 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Zhou, Cong-Shan
Yang, Tao
N′-(5-Bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide
title N′-(5-Bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide
title_full N′-(5-Bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide
title_fullStr N′-(5-Bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide
title_full_unstemmed N′-(5-Bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide
title_short N′-(5-Bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide
title_sort n′-(5-bromo-2-hydroxy­benzyl­idene)-4-chloro­benzohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983862/
https://www.ncbi.nlm.nih.gov/pubmed/21580596
http://dx.doi.org/10.1107/S160053681000752X
work_keys_str_mv AT zhoucongshan n5bromo2hydroxybenzylidene4chlorobenzohydrazide
AT yangtao n5bromo2hydroxybenzylidene4chlorobenzohydrazide

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