Bis(3,5-dinitro­benzoato-κO (1))tetra­methano­lcobalt(II)

The Co(II) atom (site symmetry [Image: see text]) in the title complex, [Co(C(7)H(3)N(2)O(6))(2)(CH(3)OH)(4)], exists within an octa­hedral O(6) donor set defined by two O-monodentate 3,5-dinitro­benzoate anions and four methanol O atoms. An intra­molecular O(m)—H⋯O(c) (m = methanol and c = carbon­y...

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Detalles Bibliográficos
Autores principales: Sarkar, Bipasa, Roy, Abhijit, Ng, Seik Weng, Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983864/
https://www.ncbi.nlm.nih.gov/pubmed/21580479
http://dx.doi.org/10.1107/S1600536810007580
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author Sarkar, Bipasa
Roy, Abhijit
Ng, Seik Weng
Tiekink, Edward R. T.
author_facet Sarkar, Bipasa
Roy, Abhijit
Ng, Seik Weng
Tiekink, Edward R. T.
author_sort Sarkar, Bipasa
collection PubMed
description The Co(II) atom (site symmetry [Image: see text]) in the title complex, [Co(C(7)H(3)N(2)O(6))(2)(CH(3)OH)(4)], exists within an octa­hedral O(6) donor set defined by two O-monodentate 3,5-dinitro­benzoate anions and four methanol O atoms. An intra­molecular O(m)—H⋯O(c) (m = methanol and c = carbon­yl) hydrogen bond leads to the formation of an S(6) ring. In the crystal, centrosymmetrically related mol­ecules associate via further O(m)—H⋯O(c) hydrogen bonds, leading to linear supra­molecular chains propagating along the a-axis direction.
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spelling pubmed-29838642010-12-30 Bis(3,5-dinitro­benzoato-κO (1))tetra­methano­lcobalt(II) Sarkar, Bipasa Roy, Abhijit Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The Co(II) atom (site symmetry [Image: see text]) in the title complex, [Co(C(7)H(3)N(2)O(6))(2)(CH(3)OH)(4)], exists within an octa­hedral O(6) donor set defined by two O-monodentate 3,5-dinitro­benzoate anions and four methanol O atoms. An intra­molecular O(m)—H⋯O(c) (m = methanol and c = carbon­yl) hydrogen bond leads to the formation of an S(6) ring. In the crystal, centrosymmetrically related mol­ecules associate via further O(m)—H⋯O(c) hydrogen bonds, leading to linear supra­molecular chains propagating along the a-axis direction. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983864/ /pubmed/21580479 http://dx.doi.org/10.1107/S1600536810007580 Text en © Sarkar et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Sarkar, Bipasa
Roy, Abhijit
Ng, Seik Weng
Tiekink, Edward R. T.
Bis(3,5-dinitro­benzoato-κO (1))tetra­methano­lcobalt(II)
title Bis(3,5-dinitro­benzoato-κO (1))tetra­methano­lcobalt(II)
title_full Bis(3,5-dinitro­benzoato-κO (1))tetra­methano­lcobalt(II)
title_fullStr Bis(3,5-dinitro­benzoato-κO (1))tetra­methano­lcobalt(II)
title_full_unstemmed Bis(3,5-dinitro­benzoato-κO (1))tetra­methano­lcobalt(II)
title_short Bis(3,5-dinitro­benzoato-κO (1))tetra­methano­lcobalt(II)
title_sort bis(3,5-dinitro­benzoato-κo (1))tetra­methano­lcobalt(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983864/
https://www.ncbi.nlm.nih.gov/pubmed/21580479
http://dx.doi.org/10.1107/S1600536810007580
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AT ngseikweng bis35dinitrobenzoatoko1tetramethanolcobaltii
AT tiekinkedwardrt bis35dinitrobenzoatoko1tetramethanolcobaltii

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