Tetra­phenyl­phospho­nium octa­hydro­triborate

The structure of the title salt, C(24)H(20)P(+)·H(8)B(3) (−), at 120 (2) K has triclinic (P1) symmetry with an unusual Z = 5, although there is pseudosymmetry observed with the tetraphenylphosphonium cations exhibiting I [Image: see text] symmetry. One of the anions is disordered over two sets of si...

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Detalles Bibliográficos
Autores principales: Beckett, Michael A., Horton, Peter N., Hursthouse, Michael B., Pszolla, Christian
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983874/
https://www.ncbi.nlm.nih.gov/pubmed/21580660
http://dx.doi.org/10.1107/S1600536810008263
Descripción
Sumario:The structure of the title salt, C(24)H(20)P(+)·H(8)B(3) (−), at 120 (2) K has triclinic (P1) symmetry with an unusual Z = 5, although there is pseudosymmetry observed with the tetraphenylphosphonium cations exhibiting I [Image: see text] symmetry. One of the anions is disordered over two sets of sites with refined occupancies of 0.478 (11) and 0.522 (11).

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