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Tetraphenylphosphonium octahydrotriborate
The structure of the title salt, C(24)H(20)P(+)·H(8)B(3) (−), at 120 (2) K has triclinic (P1) symmetry with an unusual Z = 5, although there is pseudosymmetry observed with the tetraphenylphosphonium cations exhibiting I [Image: see text] symmetry. One of the anions is disordered over two sets of si...
| Autores principales: | , , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983874/ https://www.ncbi.nlm.nih.gov/pubmed/21580660 http://dx.doi.org/10.1107/S1600536810008263 |
| _version_ | 1782191979278368768 |
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| author | Beckett, Michael A. Horton, Peter N. Hursthouse, Michael B. Pszolla, Christian |
| author_facet | Beckett, Michael A. Horton, Peter N. Hursthouse, Michael B. Pszolla, Christian |
| author_sort | Beckett, Michael A. |
| collection | PubMed |
| description | The structure of the title salt, C(24)H(20)P(+)·H(8)B(3) (−), at 120 (2) K has triclinic (P1) symmetry with an unusual Z = 5, although there is pseudosymmetry observed with the tetraphenylphosphonium cations exhibiting I [Image: see text] symmetry. One of the anions is disordered over two sets of sites with refined occupancies of 0.478 (11) and 0.522 (11). |
| format | Text |
| id | pubmed-2983874 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29838742010-12-30 Tetraphenylphosphonium octahydrotriborate Beckett, Michael A. Horton, Peter N. Hursthouse, Michael B. Pszolla, Christian Acta Crystallogr Sect E Struct Rep Online Organic Papers The structure of the title salt, C(24)H(20)P(+)·H(8)B(3) (−), at 120 (2) K has triclinic (P1) symmetry with an unusual Z = 5, although there is pseudosymmetry observed with the tetraphenylphosphonium cations exhibiting I [Image: see text] symmetry. One of the anions is disordered over two sets of sites with refined occupancies of 0.478 (11) and 0.522 (11). International Union of Crystallography 2010-03-13 /pmc/articles/PMC2983874/ /pubmed/21580660 http://dx.doi.org/10.1107/S1600536810008263 Text en © Beckett et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Organic Papers Beckett, Michael A. Horton, Peter N. Hursthouse, Michael B. Pszolla, Christian Tetraphenylphosphonium octahydrotriborate |
| title | Tetraphenylphosphonium octahydrotriborate |
| title_full | Tetraphenylphosphonium octahydrotriborate |
| title_fullStr | Tetraphenylphosphonium octahydrotriborate |
| title_full_unstemmed | Tetraphenylphosphonium octahydrotriborate |
| title_short | Tetraphenylphosphonium octahydrotriborate |
| title_sort | tetraphenylphosphonium octahydrotriborate |
| topic | Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983874/ https://www.ncbi.nlm.nih.gov/pubmed/21580660 http://dx.doi.org/10.1107/S1600536810008263 |
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