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catena-Poly[[[bis(2,2′-bipyridine)manganese(II)]-μ(4)-3,3′-sulfanediyldipropionato] bis(perchlorate)]
The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2′-bipyridine ligands and two O atoms of two different 3,3′-sulfanediyldipro...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983876/ https://www.ncbi.nlm.nih.gov/pubmed/21580490 http://dx.doi.org/10.1107/S1600536810008123 |
Sumario: | The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2′-bipyridine ligands and two O atoms of two different 3,3′-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions. The two carboxylate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional chains extending along [010]. |
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