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catena-Poly[[[bis­(2,2′-bipyridine)manganese(II)]-μ(4)-3,3′-sulfanediyldipropionato] bis­(perchlorate)]

The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2′-bipyridine ligands and two O atoms of two different 3,3′-sulfanediyldipro...

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Detalles Bibliográficos
Autor principal: Yong, Li
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983876/
https://www.ncbi.nlm.nih.gov/pubmed/21580490
http://dx.doi.org/10.1107/S1600536810008123
Descripción
Sumario:The title compound, [Mn(2)(C(6)H(8)O(4)S)(C(10)H(8)N(2))(4)](ClO(4))(2), which was crystallized from an aqueous solution, features two Mn(II) atoms in the asymmetric unit, each being coordinated by four N-atom donors from 2,2′-bipyridine ligands and two O atoms of two different 3,3′-sulfanediyldipropionate (L) ligands, with the O atoms in cis positions. The two carboxyl­ate groups of each L ligand, which adopt a syn-anti coordination mode, combine with four Mn(II) atoms, yielding one-dimensional chains extending along [010].