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Poly[[bis­{μ(3)-tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine}copper(II)] bis­(perchlorate)]

In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetra­zole N(4) atoms of six symmetry-equivalent tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine ligands (t (3) z) in the form of a Jahn–Teller-distorted octa­hedron with C...

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Detalles Bibliográficos
Autores principales: Werner, Franz, Tokuno, Kenji, Hasegawa, Miki, Linert, Wolfgang, Mereiter, Kurt
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983878/
https://www.ncbi.nlm.nih.gov/pubmed/21580502
http://dx.doi.org/10.1107/S1600536810008998
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author Werner, Franz
Tokuno, Kenji
Hasegawa, Miki
Linert, Wolfgang
Mereiter, Kurt
author_facet Werner, Franz
Tokuno, Kenji
Hasegawa, Miki
Linert, Wolfgang
Mereiter, Kurt
author_sort Werner, Franz
collection PubMed
description In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetra­zole N(4) atoms of six symmetry-equivalent tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine ligands (t (3) z) in the form of a Jahn–Teller-distorted octa­hedron with Cu—N bond distances of 2.0210 (8), 2.0259 (8) and 2.4098 (8) Å. The tertiary amine N atom is stereochemically inactive. The cationic part of the structure, viz. [Cu(t (3) z)(2)](2+), forms an infinite two-dimensional network parallel to (100), in pockets of which the perchlorate anions reside. The individual networks are partially inter­locked and held together by C—H⋯O inter­actions to the perchlorate anions and C—H⋯N inter­actions to tetra­zole N atoms.
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spelling pubmed-29838782010-12-30 Poly[[bis­{μ(3)-tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine}copper(II)] bis­(perchlorate)] Werner, Franz Tokuno, Kenji Hasegawa, Miki Linert, Wolfgang Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetra­zole N(4) atoms of six symmetry-equivalent tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine ligands (t (3) z) in the form of a Jahn–Teller-distorted octa­hedron with Cu—N bond distances of 2.0210 (8), 2.0259 (8) and 2.4098 (8) Å. The tertiary amine N atom is stereochemically inactive. The cationic part of the structure, viz. [Cu(t (3) z)(2)](2+), forms an infinite two-dimensional network parallel to (100), in pockets of which the perchlorate anions reside. The individual networks are partially inter­locked and held together by C—H⋯O inter­actions to the perchlorate anions and C—H⋯N inter­actions to tetra­zole N atoms. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2983878/ /pubmed/21580502 http://dx.doi.org/10.1107/S1600536810008998 Text en © Werner et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Werner, Franz
Tokuno, Kenji
Hasegawa, Miki
Linert, Wolfgang
Mereiter, Kurt
Poly[[bis­{μ(3)-tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine}copper(II)] bis­(perchlorate)]
title Poly[[bis­{μ(3)-tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine}copper(II)] bis­(perchlorate)]
title_full Poly[[bis­{μ(3)-tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine}copper(II)] bis­(perchlorate)]
title_fullStr Poly[[bis­{μ(3)-tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine}copper(II)] bis­(perchlorate)]
title_full_unstemmed Poly[[bis­{μ(3)-tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine}copper(II)] bis­(perchlorate)]
title_short Poly[[bis­{μ(3)-tris­[2-(1H-tetra­zol-1-yl)eth­yl]amine}copper(II)] bis­(perchlorate)]
title_sort poly[[bis­{μ(3)-tris­[2-(1h-tetra­zol-1-yl)eth­yl]amine}copper(ii)] bis­(perchlorate)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983878/
https://www.ncbi.nlm.nih.gov/pubmed/21580502
http://dx.doi.org/10.1107/S1600536810008998
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