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Poly[[bis{μ(3)-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)]
In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetrazole N(4) atoms of six symmetry-equivalent tris[2-(1H-tetrazol-1-yl)ethyl]amine ligands (t (3) z) in the form of a Jahn–Teller-distorted octahedron with C...
Autores principales: | , , , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983878/ https://www.ncbi.nlm.nih.gov/pubmed/21580502 http://dx.doi.org/10.1107/S1600536810008998 |
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author | Werner, Franz Tokuno, Kenji Hasegawa, Miki Linert, Wolfgang Mereiter, Kurt |
author_facet | Werner, Franz Tokuno, Kenji Hasegawa, Miki Linert, Wolfgang Mereiter, Kurt |
author_sort | Werner, Franz |
collection | PubMed |
description | In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetrazole N(4) atoms of six symmetry-equivalent tris[2-(1H-tetrazol-1-yl)ethyl]amine ligands (t (3) z) in the form of a Jahn–Teller-distorted octahedron with Cu—N bond distances of 2.0210 (8), 2.0259 (8) and 2.4098 (8) Å. The tertiary amine N atom is stereochemically inactive. The cationic part of the structure, viz. [Cu(t (3) z)(2)](2+), forms an infinite two-dimensional network parallel to (100), in pockets of which the perchlorate anions reside. The individual networks are partially interlocked and held together by C—H⋯O interactions to the perchlorate anions and C—H⋯N interactions to tetrazole N atoms. |
format | Text |
id | pubmed-2983878 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29838782010-12-30 Poly[[bis{μ(3)-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)] Werner, Franz Tokuno, Kenji Hasegawa, Miki Linert, Wolfgang Mereiter, Kurt Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, {[Cu(C(9)H(15)N(13))(2)](ClO(4))(2)}(n), the Cu(2+) cation lies on an inversion center and is coordinated by the tetrazole N(4) atoms of six symmetry-equivalent tris[2-(1H-tetrazol-1-yl)ethyl]amine ligands (t (3) z) in the form of a Jahn–Teller-distorted octahedron with Cu—N bond distances of 2.0210 (8), 2.0259 (8) and 2.4098 (8) Å. The tertiary amine N atom is stereochemically inactive. The cationic part of the structure, viz. [Cu(t (3) z)(2)](2+), forms an infinite two-dimensional network parallel to (100), in pockets of which the perchlorate anions reside. The individual networks are partially interlocked and held together by C—H⋯O interactions to the perchlorate anions and C—H⋯N interactions to tetrazole N atoms. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2983878/ /pubmed/21580502 http://dx.doi.org/10.1107/S1600536810008998 Text en © Werner et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Werner, Franz Tokuno, Kenji Hasegawa, Miki Linert, Wolfgang Mereiter, Kurt Poly[[bis{μ(3)-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)] |
title | Poly[[bis{μ(3)-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)] |
title_full | Poly[[bis{μ(3)-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)] |
title_fullStr | Poly[[bis{μ(3)-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)] |
title_full_unstemmed | Poly[[bis{μ(3)-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)] |
title_short | Poly[[bis{μ(3)-tris[2-(1H-tetrazol-1-yl)ethyl]amine}copper(II)] bis(perchlorate)] |
title_sort | poly[[bis{μ(3)-tris[2-(1h-tetrazol-1-yl)ethyl]amine}copper(ii)] bis(perchlorate)] |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983878/ https://www.ncbi.nlm.nih.gov/pubmed/21580502 http://dx.doi.org/10.1107/S1600536810008998 |
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