Triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(II) dihydrate

The title compound, [Co(C(14)H(6)N(2)O(4))(H(2)O)(3)]·2H(2)O, has two­fold crystallographic symmetry. The Co(II) atom is in a distorted penta­gonal-bipyramidal coordination environment with two N atoms and two O atoms from a tetradentate 1,10-phenanthroline-2,9-dicarboxyl­ate ligand and one O atom f...

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Detalles Bibliográficos
Autores principales: Shi, Zi-Fa, Gao, Zhu-Qing, Gu, Jin-Zhong
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983888/
https://www.ncbi.nlm.nih.gov/pubmed/21580484
http://dx.doi.org/10.1107/S1600536810007567
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author Shi, Zi-Fa
Gao, Zhu-Qing
Gu, Jin-Zhong
author_facet Shi, Zi-Fa
Gao, Zhu-Qing
Gu, Jin-Zhong
author_sort Shi, Zi-Fa
collection PubMed
description The title compound, [Co(C(14)H(6)N(2)O(4))(H(2)O)(3)]·2H(2)O, has two­fold crystallographic symmetry. The Co(II) atom is in a distorted penta­gonal-bipyramidal coordination environment with two N atoms and two O atoms from a tetradentate 1,10-phenanthroline-2,9-dicarboxyl­ate ligand and one O atom from a water mol­ecule forming the penta­gonal plane, and two O atoms from two water mol­ecules occupying axial positions. In the crystal, adjacent mol­ecules are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network.
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spelling pubmed-29838882010-12-30 Triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(II) dihydrate Shi, Zi-Fa Gao, Zhu-Qing Gu, Jin-Zhong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Co(C(14)H(6)N(2)O(4))(H(2)O)(3)]·2H(2)O, has two­fold crystallographic symmetry. The Co(II) atom is in a distorted penta­gonal-bipyramidal coordination environment with two N atoms and two O atoms from a tetradentate 1,10-phenanthroline-2,9-dicarboxyl­ate ligand and one O atom from a water mol­ecule forming the penta­gonal plane, and two O atoms from two water mol­ecules occupying axial positions. In the crystal, adjacent mol­ecules are linked by O—H⋯O hydrogen bonds, forming a three-dimensional network. International Union of Crystallography 2010-03-06 /pmc/articles/PMC2983888/ /pubmed/21580484 http://dx.doi.org/10.1107/S1600536810007567 Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Zi-Fa
Gao, Zhu-Qing
Gu, Jin-Zhong
Triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(II) dihydrate
title Triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(II) dihydrate
title_full Triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(II) dihydrate
title_fullStr Triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(II) dihydrate
title_full_unstemmed Triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(II) dihydrate
title_short Triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(II) dihydrate
title_sort triaqua­(1,10-phenanthroline-2,9-dicarboxyl­ato)cobalt(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983888/
https://www.ncbi.nlm.nih.gov/pubmed/21580484
http://dx.doi.org/10.1107/S1600536810007567
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AT gaozhuqing triaqua110phenanthroline29dicarboxylatocobaltiidihydrate
AT gujinzhong triaqua110phenanthroline29dicarboxylatocobaltiidihydrate

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