Bis(μ-diphenyl­arsine-κ(2) As:As)bis­[tetra­carbonyl­tungsten(0)]

The title compound, [W(2)(C(12)H(10)As)(2)(CO)(8)], features a diamond-shaped W(2)As(2) core with a W—W distance of 3.0948 (7) Å. The coordination geometry for each W atom is based on a penta­gonal bipyramid within a As(2)C(4)W donor set, with carbonyl ligands defining the axial positions; the As at...

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Detalles Bibliográficos
Autores principales: Tiekink, Edward R. T., Wardell, James L.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983890/
https://www.ncbi.nlm.nih.gov/pubmed/21580478
http://dx.doi.org/10.1107/S1600536810007592
Descripción
Sumario:The title compound, [W(2)(C(12)H(10)As)(2)(CO)(8)], features a diamond-shaped W(2)As(2) core with a W—W distance of 3.0948 (7) Å. The coordination geometry for each W atom is based on a penta­gonal bipyramid within a As(2)C(4)W donor set, with carbonyl ligands defining the axial positions; the As atoms exist within distorted tetra­hedral C(2)W(2) donor sets.

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