Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate

The 1,4-dihydro­pyridine ring in the title compound, C(17)H(19)NO(5), has a flattened-boat conformation, and the benzene ring is almost orthogonal to it [dihedral angle = 82.98 (12)°]. The hydr­oxy group is disordered over two positions in a 0.780 (4):0.220 (4) ratio. In the crystal, hydrogen-bondin...

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Autores principales: Rajesh, K., Vijayakumar, V., Narasimhamurthy, T., Suresh, J., Tiekink, Edward R. T.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983893/
https://www.ncbi.nlm.nih.gov/pubmed/21580781
http://dx.doi.org/10.1107/S1600536810011268
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author Rajesh, K.
Vijayakumar, V.
Narasimhamurthy, T.
Suresh, J.
Tiekink, Edward R. T.
author_facet Rajesh, K.
Vijayakumar, V.
Narasimhamurthy, T.
Suresh, J.
Tiekink, Edward R. T.
author_sort Rajesh, K.
collection PubMed
description The 1,4-dihydro­pyridine ring in the title compound, C(17)H(19)NO(5), has a flattened-boat conformation, and the benzene ring is almost orthogonal to it [dihedral angle = 82.98 (12)°]. The hydr­oxy group is disordered over two positions in a 0.780 (4):0.220 (4) ratio. In the crystal, hydrogen-bonding inter­actions of the type N(a)—H⋯O(c) and O(h)—H⋯O(c) (a = amine, c = carbonyl and h = hydr­oxy) link the mol­ecules into a three-dimensional network.
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spelling pubmed-29838932010-12-30 Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate Rajesh, K. Vijayakumar, V. Narasimhamurthy, T. Suresh, J. Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Organic Papers The 1,4-dihydro­pyridine ring in the title compound, C(17)H(19)NO(5), has a flattened-boat conformation, and the benzene ring is almost orthogonal to it [dihedral angle = 82.98 (12)°]. The hydr­oxy group is disordered over two positions in a 0.780 (4):0.220 (4) ratio. In the crystal, hydrogen-bonding inter­actions of the type N(a)—H⋯O(c) and O(h)—H⋯O(c) (a = amine, c = carbonyl and h = hydr­oxy) link the mol­ecules into a three-dimensional network. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983893/ /pubmed/21580781 http://dx.doi.org/10.1107/S1600536810011268 Text en © Rajesh et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rajesh, K.
Vijayakumar, V.
Narasimhamurthy, T.
Suresh, J.
Tiekink, Edward R. T.
Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_full Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_fullStr Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_full_unstemmed Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_short Dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
title_sort dimethyl 4-(3-hydroxy­phen­yl)-2,6-dimethyl-1,4-dihydro­pyridine-3,5-dicarboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983893/
https://www.ncbi.nlm.nih.gov/pubmed/21580781
http://dx.doi.org/10.1107/S1600536810011268
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AT sureshj dimethyl43hydroxyphenyl26dimethyl14dihydropyridine35dicarboxylate
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