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1-(6-Ferrocenylhexyl)-1H-imidazole
The title compound, [Fe(C(5)H(5))(C(14)H(19)N(2))], is characterized by a ferrocenyl group separated from an imidazole functionality by a straight-chain hexyl unit. The two cyclopentadienyl rings of the ferrocenyl group show a marginal inward tilt of 2.17 (2)°. The imidazole unit, which is essenti...
| Autores principales: | , , |
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983896/ https://www.ncbi.nlm.nih.gov/pubmed/21580511 http://dx.doi.org/10.1107/S1600536810007737 |
| _version_ | 1782191984642883584 |
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| author | Nyamori, Vincent O. Bala, Muhammad D. Levendis, Demetrius C. |
| author_facet | Nyamori, Vincent O. Bala, Muhammad D. Levendis, Demetrius C. |
| author_sort | Nyamori, Vincent O. |
| collection | PubMed |
| description | The title compound, [Fe(C(5)H(5))(C(14)H(19)N(2))], is characterized by a ferrocenyl group separated from an imidazole functionality by a straight-chain hexyl unit. The two cyclopentadienyl rings of the ferrocenyl group show a marginal inward tilt of 2.17 (2)°. The imidazole unit, which is essentially planar (with a maximum deviation of 0.007 A for one of the N atoms) and tilted away from the ferrocenyl group [dihedral angle between the substituted ferrocenyl ring and the imidazole = 122.6 (1)°], is involved in intermolecular C—H⋯N interactions. |
| format | Text |
| id | pubmed-2983896 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29838962010-12-30 1-(6-Ferrocenylhexyl)-1H-imidazole Nyamori, Vincent O. Bala, Muhammad D. Levendis, Demetrius C. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(14)H(19)N(2))], is characterized by a ferrocenyl group separated from an imidazole functionality by a straight-chain hexyl unit. The two cyclopentadienyl rings of the ferrocenyl group show a marginal inward tilt of 2.17 (2)°. The imidazole unit, which is essentially planar (with a maximum deviation of 0.007 A for one of the N atoms) and tilted away from the ferrocenyl group [dihedral angle between the substituted ferrocenyl ring and the imidazole = 122.6 (1)°], is involved in intermolecular C—H⋯N interactions. International Union of Crystallography 2010-03-17 /pmc/articles/PMC2983896/ /pubmed/21580511 http://dx.doi.org/10.1107/S1600536810007737 Text en © Nyamori et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Nyamori, Vincent O. Bala, Muhammad D. Levendis, Demetrius C. 1-(6-Ferrocenylhexyl)-1H-imidazole |
| title | 1-(6-Ferrocenylhexyl)-1H-imidazole |
| title_full | 1-(6-Ferrocenylhexyl)-1H-imidazole |
| title_fullStr | 1-(6-Ferrocenylhexyl)-1H-imidazole |
| title_full_unstemmed | 1-(6-Ferrocenylhexyl)-1H-imidazole |
| title_short | 1-(6-Ferrocenylhexyl)-1H-imidazole |
| title_sort | 1-(6-ferrocenylhexyl)-1h-imidazole |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983896/ https://www.ncbi.nlm.nih.gov/pubmed/21580511 http://dx.doi.org/10.1107/S1600536810007737 |
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