Cargando…
N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate
In the title compound, C(18)H(20)N(4)O(3)·H(2)O, the two aromatic rings are linked through a methylidenehydrazide fragment, which is fully extended with C—C—N—N, C—N—N=C and N—N=C—C torsion angles of 179.4 (2), 174.7 (2) and 178.3 (2)°, respectively. The dihedral angle between the two aromatic ring...
Autores principales: | , , , , |
---|---|
Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983899/ https://www.ncbi.nlm.nih.gov/pubmed/21580570 http://dx.doi.org/10.1107/S1600536810011554 |
_version_ | 1782191985347526656 |
---|---|
author | Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Rizvi, Syed Umar Farooq Parvez, Masood |
author_facet | Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Rizvi, Syed Umar Farooq Parvez, Masood |
author_sort | Ahmad, Tanveer |
collection | PubMed |
description | In the title compound, C(18)H(20)N(4)O(3)·H(2)O, the two aromatic rings are linked through a methylidenehydrazide fragment, which is fully extended with C—C—N—N, C—N—N=C and N—N=C—C torsion angles of 179.4 (2), 174.7 (2) and 178.3 (2)°, respectively. The dihedral angle between the two aromatic rings is 7.01 (8)°. In the crystal structure, the water of hydration is involved in extensive hydrogen bonding. Intermolecular O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds link the components of the structure into a two-dimensional network and additional stabilization is provided by weak intermolecular C—H⋯O hydrogen bonds. |
format | Text |
id | pubmed-2983899 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2010 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-29838992010-12-30 N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Rizvi, Syed Umar Farooq Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(20)N(4)O(3)·H(2)O, the two aromatic rings are linked through a methylidenehydrazide fragment, which is fully extended with C—C—N—N, C—N—N=C and N—N=C—C torsion angles of 179.4 (2), 174.7 (2) and 178.3 (2)°, respectively. The dihedral angle between the two aromatic rings is 7.01 (8)°. In the crystal structure, the water of hydration is involved in extensive hydrogen bonding. Intermolecular O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds link the components of the structure into a two-dimensional network and additional stabilization is provided by weak intermolecular C—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983899/ /pubmed/21580570 http://dx.doi.org/10.1107/S1600536810011554 Text en © Ahmad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Rizvi, Syed Umar Farooq Parvez, Masood N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate |
title |
N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate |
title_full |
N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate |
title_fullStr |
N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate |
title_full_unstemmed |
N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate |
title_short |
N′-[(E)-4-(Diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate |
title_sort | n′-[(e)-4-(diethylamino)benzylidene]-4-nitrobenzohydrazide monohydrate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983899/ https://www.ncbi.nlm.nih.gov/pubmed/21580570 http://dx.doi.org/10.1107/S1600536810011554 |
work_keys_str_mv | AT ahmadtanveer ne4diethylaminobenzylidene4nitrobenzohydrazidemonohydrate AT ziaurrehmanmuhammad ne4diethylaminobenzylidene4nitrobenzohydrazidemonohydrate AT siddiquihamidlatif ne4diethylaminobenzylidene4nitrobenzohydrazidemonohydrate AT rizvisyedumarfarooq ne4diethylaminobenzylidene4nitrobenzohydrazidemonohydrate AT parvezmasood ne4diethylaminobenzylidene4nitrobenzohydrazidemonohydrate |