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N′-[(E)-4-(Diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate

In the title compound, C(18)H(20)N(4)O(3)·H(2)O, the two aromatic rings are linked through a methyl­idenehydrazide fragment, which is fully extended with C—C—N—N, C—N—N=C and N—N=C—C torsion angles of 179.4 (2), 174.7 (2) and 178.3 (2)°, respectively. The dihedral angle between the two aromatic ring...

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Autores principales: Ahmad, Tanveer, Zia-ur-Rehman, Muhammad, Siddiqui, Hamid Latif, Rizvi, Syed Umar Farooq, Parvez, Masood
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983899/
https://www.ncbi.nlm.nih.gov/pubmed/21580570
http://dx.doi.org/10.1107/S1600536810011554
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author Ahmad, Tanveer
Zia-ur-Rehman, Muhammad
Siddiqui, Hamid Latif
Rizvi, Syed Umar Farooq
Parvez, Masood
author_facet Ahmad, Tanveer
Zia-ur-Rehman, Muhammad
Siddiqui, Hamid Latif
Rizvi, Syed Umar Farooq
Parvez, Masood
author_sort Ahmad, Tanveer
collection PubMed
description In the title compound, C(18)H(20)N(4)O(3)·H(2)O, the two aromatic rings are linked through a methyl­idenehydrazide fragment, which is fully extended with C—C—N—N, C—N—N=C and N—N=C—C torsion angles of 179.4 (2), 174.7 (2) and 178.3 (2)°, respectively. The dihedral angle between the two aromatic rings is 7.01 (8)°. In the crystal structure, the water of hydration is involved in extensive hydrogen bonding. Inter­molecular O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds link the components of the structure into a two-dimensional network and additional stabilization is provided by weak inter­molecular C—H⋯O hydrogen bonds.
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spelling pubmed-29838992010-12-30 N′-[(E)-4-(Diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate Ahmad, Tanveer Zia-ur-Rehman, Muhammad Siddiqui, Hamid Latif Rizvi, Syed Umar Farooq Parvez, Masood Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(20)N(4)O(3)·H(2)O, the two aromatic rings are linked through a methyl­idenehydrazide fragment, which is fully extended with C—C—N—N, C—N—N=C and N—N=C—C torsion angles of 179.4 (2), 174.7 (2) and 178.3 (2)°, respectively. The dihedral angle between the two aromatic rings is 7.01 (8)°. In the crystal structure, the water of hydration is involved in extensive hydrogen bonding. Inter­molecular O—H⋯O, N—H⋯O and O—H⋯N hydrogen bonds link the components of the structure into a two-dimensional network and additional stabilization is provided by weak inter­molecular C—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983899/ /pubmed/21580570 http://dx.doi.org/10.1107/S1600536810011554 Text en © Ahmad et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ahmad, Tanveer
Zia-ur-Rehman, Muhammad
Siddiqui, Hamid Latif
Rizvi, Syed Umar Farooq
Parvez, Masood
N′-[(E)-4-(Diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate
title N′-[(E)-4-(Diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_full N′-[(E)-4-(Diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_fullStr N′-[(E)-4-(Diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_full_unstemmed N′-[(E)-4-(Diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_short N′-[(E)-4-(Diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate
title_sort n′-[(e)-4-(diethyl­amino)benzyl­idene]-4-nitro­benzohydrazide monohydrate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983899/
https://www.ncbi.nlm.nih.gov/pubmed/21580570
http://dx.doi.org/10.1107/S1600536810011554
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