Methoxo[N′-(3-meth­oxy-2-oxidobenzyl­idene)benzohydrazidato]oxidovanadium(V)

In the title complex, [V(C(15)H(12)N(2)O(4))(CH(3)O)O], the V(V) ion exhibits a distorted square-pyramidal coordination geometry; three donor atoms from a hydrazone ligand and one O atom of the deprotonated methanol define the coordination basal plane. The V(V) ion is displaced by 0.464 (1) Å from t...

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Detalles Bibliográficos
Autores principales: Huang, Shu-Mei, Jiang, Fei-Feng, Chen, Xiao-Hua, Wu, Qiong-Jie
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983900/
https://www.ncbi.nlm.nih.gov/pubmed/21580542
http://dx.doi.org/10.1107/S1600536810009608
Descripción
Sumario:In the title complex, [V(C(15)H(12)N(2)O(4))(CH(3)O)O], the V(V) ion exhibits a distorted square-pyramidal coordination geometry; three donor atoms from a hydrazone ligand and one O atom of the deprotonated methanol define the coordination basal plane. The V(V) ion is displaced by 0.464 (1) Å from the basal plane towards the axial oxide O atom. Intra­molecular O—H⋯N hydrogen bonding occurs. Inter­molecular C—H⋯O hydrogen bonding is also observed in the crystal structure.

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