endo-3,3-Dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate

The relative configuration of the endo isomer of the title compound, C(9)H(14)O(4)S, has been established and the conformation of the diastereoisomer is discussed. The five-membered ring adopts an envelope conformation. The conformation of the methane­sulfonate substituent is stabilized by inter­mol...

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Detalles Bibliográficos
Autores principales: Kremer, Adrian, Norberg, Bernadette, Krief, Alain, Wouters, Johan
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983904/
https://www.ncbi.nlm.nih.gov/pubmed/21580752
http://dx.doi.org/10.1107/S1600536810010901
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author Kremer, Adrian
Norberg, Bernadette
Krief, Alain
Wouters, Johan
author_facet Kremer, Adrian
Norberg, Bernadette
Krief, Alain
Wouters, Johan
author_sort Kremer, Adrian
collection PubMed
description The relative configuration of the endo isomer of the title compound, C(9)H(14)O(4)S, has been established and the conformation of the diastereoisomer is discussed. The five-membered ring adopts an envelope conformation. The conformation of the methane­sulfonate substituent is stabilized by inter­molecular C—H⋯O hydrogen bonds. The crystal packing results in alternating layers of polar methane­sulfonates and stacked bicyclo­hexa­nyl rings parallel to ab.
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spelling pubmed-29839042010-12-30 endo-3,3-Dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate Kremer, Adrian Norberg, Bernadette Krief, Alain Wouters, Johan Acta Crystallogr Sect E Struct Rep Online Organic Papers The relative configuration of the endo isomer of the title compound, C(9)H(14)O(4)S, has been established and the conformation of the diastereoisomer is discussed. The five-membered ring adopts an envelope conformation. The conformation of the methane­sulfonate substituent is stabilized by inter­molecular C—H⋯O hydrogen bonds. The crystal packing results in alternating layers of polar methane­sulfonates and stacked bicyclo­hexa­nyl rings parallel to ab. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2983904/ /pubmed/21580752 http://dx.doi.org/10.1107/S1600536810010901 Text en © Kremer et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Kremer, Adrian
Norberg, Bernadette
Krief, Alain
Wouters, Johan
endo-3,3-Dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate
title endo-3,3-Dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate
title_full endo-3,3-Dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate
title_fullStr endo-3,3-Dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate
title_full_unstemmed endo-3,3-Dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate
title_short endo-3,3-Dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate
title_sort endo-3,3-dimethyl-4-oxobicyclo­[3.1.0]hexan-2-yl methane­sulfonate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983904/
https://www.ncbi.nlm.nih.gov/pubmed/21580752
http://dx.doi.org/10.1107/S1600536810010901
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AT norbergbernadette endo33dimethyl4oxobicyclo310hexan2ylmethanesulfonate
AT kriefalain endo33dimethyl4oxobicyclo310hexan2ylmethanesulfonate
AT woutersjohan endo33dimethyl4oxobicyclo310hexan2ylmethanesulfonate

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