{6-[(2-Anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κN)­copper(II)

In the title complex, [Cu(C(17)H(19)N(2)O(2))(NCS)], the Cu(II) atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-eth­oxy-6-[(2-anilino­ethyl)­iminometh­yl]phenolate ligand, and by the N atom of a thio­cyanate anion, forming a distorted CuON(3...

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Detalles Bibliográficos
Autores principales: Wang, Chen-Yi, Li, Jing-Fen, Cao, Feng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983905/
https://www.ncbi.nlm.nih.gov/pubmed/21580535
http://dx.doi.org/10.1107/S1600536810010305
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author Wang, Chen-Yi
Li, Jing-Fen
Cao, Feng
author_facet Wang, Chen-Yi
Li, Jing-Fen
Cao, Feng
author_sort Wang, Chen-Yi
collection PubMed
description In the title complex, [Cu(C(17)H(19)N(2)O(2))(NCS)], the Cu(II) atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-eth­oxy-6-[(2-anilino­ethyl)­iminometh­yl]phenolate ligand, and by the N atom of a thio­cyanate anion, forming a distorted CuON(3) square-planar geometry. The dihedral angle between the aromatic rings of the ligand is 67.9 (4)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds occur, generating R (2) (2)(8) loops.
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spelling pubmed-29839052010-12-30 {6-[(2-Anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κN)­copper(II) Wang, Chen-Yi Li, Jing-Fen Cao, Feng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Cu(C(17)H(19)N(2)O(2))(NCS)], the Cu(II) atom is chelated by the phenolate O atom, the imine N atom and the amine N atom of the N,N′,O-tridentate 2-eth­oxy-6-[(2-anilino­ethyl)­iminometh­yl]phenolate ligand, and by the N atom of a thio­cyanate anion, forming a distorted CuON(3) square-planar geometry. The dihedral angle between the aromatic rings of the ligand is 67.9 (4)°. In the crystal, inversion dimers linked by pairs of N—H⋯O hydrogen bonds occur, generating R (2) (2)(8) loops. International Union of Crystallography 2010-03-24 /pmc/articles/PMC2983905/ /pubmed/21580535 http://dx.doi.org/10.1107/S1600536810010305 Text en © Wang et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Wang, Chen-Yi
Li, Jing-Fen
Cao, Feng
{6-[(2-Anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κN)­copper(II)
title {6-[(2-Anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κN)­copper(II)
title_full {6-[(2-Anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κN)­copper(II)
title_fullStr {6-[(2-Anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κN)­copper(II)
title_full_unstemmed {6-[(2-Anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κN)­copper(II)
title_short {6-[(2-Anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κN)­copper(II)
title_sort {6-[(2-anilinoeth­yl)imino­meth­yl]-2-eth­oxyphenolato}(thio­cyanato-κn)­copper(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983905/
https://www.ncbi.nlm.nih.gov/pubmed/21580535
http://dx.doi.org/10.1107/S1600536810010305
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AT lijingfen 62anilinoethyliminomethyl2ethoxyphenolatothiocyanatokncopperii
AT caofeng 62anilinoethyliminomethyl2ethoxyphenolatothiocyanatokncopperii

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