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2-Ferrocenyl-N-(6-methyl-2-pyridyl)benzamide
The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methylpyridine, crystallizes with two dissimilar molecules in the asymmetric unit. In one molecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiet...
Autores principales: | , , |
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983907/ https://www.ncbi.nlm.nih.gov/pubmed/21580500 http://dx.doi.org/10.1107/S1600536810008342 |
Sumario: | The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methylpyridine, crystallizes with two dissimilar molecules in the asymmetric unit. In one molecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, molecules aggregate into dimers via cyclic, asymmetric N—H⋯N interactions with graph set R (2) (2)(8), and are further augmented via intramolecular C—H⋯O=C and interdimer C—H⋯π(arene) interactions. Dimers are linked into chains along the [102] direction via weak C—H⋯O hydrogen bonds. |
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