2-Ferrocenyl-N-(6-methyl-2-pyrid­yl)benzamide

The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methyl­pyridine, crystallizes with two dissimilar mol­ecules in the asymmetric unit. In one mol­ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiet...

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Detalles Bibliográficos
Autores principales: Gallagher, John F., Alley, Steven, Lough, Alan J.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983907/
https://www.ncbi.nlm.nih.gov/pubmed/21580500
http://dx.doi.org/10.1107/S1600536810008342
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author Gallagher, John F.
Alley, Steven
Lough, Alan J.
author_facet Gallagher, John F.
Alley, Steven
Lough, Alan J.
author_sort Gallagher, John F.
collection PubMed
description The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methyl­pyridine, crystallizes with two dissimilar mol­ecules in the asymmetric unit. In one mol­ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, mol­ecules aggregate into dimers via cyclic, asymmetric N—H⋯N inter­actions with graph set R (2) (2)(8), and are further augmented via intra­molecular C—H⋯O=C and inter­dimer C—H⋯π(arene) inter­actions. Dimers are linked into chains along the [102] direction via weak C—H⋯O hydrogen bonds.
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spelling pubmed-29839072010-12-30 2-Ferrocenyl-N-(6-methyl-2-pyrid­yl)benzamide Gallagher, John F. Alley, Steven Lough, Alan J. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Fe(C(5)H(5))(C(18)H(15)N(2)O)], a product of the reaction of 2-ferrocenylbenzoic acid and 2-amino-6-methyl­pyridine, crystallizes with two dissimilar mol­ecules in the asymmetric unit. In one mol­ecule, the picoline amide group is directed away from the 2-ferrocenylbenzene moiety (anti) whereas in the other, these are proximate (syn). In the crystal structure, mol­ecules aggregate into dimers via cyclic, asymmetric N—H⋯N inter­actions with graph set R (2) (2)(8), and are further augmented via intra­molecular C—H⋯O=C and inter­dimer C—H⋯π(arene) inter­actions. Dimers are linked into chains along the [102] direction via weak C—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-13 /pmc/articles/PMC2983907/ /pubmed/21580500 http://dx.doi.org/10.1107/S1600536810008342 Text en © Gallagher et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Gallagher, John F.
Alley, Steven
Lough, Alan J.
2-Ferrocenyl-N-(6-methyl-2-pyrid­yl)benzamide
title 2-Ferrocenyl-N-(6-methyl-2-pyrid­yl)benzamide
title_full 2-Ferrocenyl-N-(6-methyl-2-pyrid­yl)benzamide
title_fullStr 2-Ferrocenyl-N-(6-methyl-2-pyrid­yl)benzamide
title_full_unstemmed 2-Ferrocenyl-N-(6-methyl-2-pyrid­yl)benzamide
title_short 2-Ferrocenyl-N-(6-methyl-2-pyrid­yl)benzamide
title_sort 2-ferrocenyl-n-(6-methyl-2-pyrid­yl)benzamide
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983907/
https://www.ncbi.nlm.nih.gov/pubmed/21580500
http://dx.doi.org/10.1107/S1600536810008342
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AT alleysteven 2ferrocenyln6methyl2pyridylbenzamide
AT loughalanj 2ferrocenyln6methyl2pyridylbenzamide

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