2-(2-Fluoro­biphenyl-4-yl)-N′-(propan-2-yl­idene)propanohydrazide

In the title compound, C(18)H(19)FN(2)O, the hydrazide side chain is approximately perpendicular to the central ring [dihedral angle = 76.80 (5)°]. The F atom is disordered over two positions with occupancies of 0.818 (2) and 0.182 (2). The packing consists of chains of mol­ecules parallel to the a...

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Detalles Bibliográficos
Autores principales: Khanum, Saira, Farman, Muhammad, Rama, Nasim Hasan, Hameed, Shahid, Jones, Peter G.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983908/
https://www.ncbi.nlm.nih.gov/pubmed/21580681
http://dx.doi.org/10.1107/S1600536810009049
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author Khanum, Saira
Farman, Muhammad
Rama, Nasim Hasan
Hameed, Shahid
Jones, Peter G.
author_facet Khanum, Saira
Farman, Muhammad
Rama, Nasim Hasan
Hameed, Shahid
Jones, Peter G.
author_sort Khanum, Saira
collection PubMed
description In the title compound, C(18)H(19)FN(2)O, the hydrazide side chain is approximately perpendicular to the central ring [dihedral angle = 76.80 (5)°]. The F atom is disordered over two positions with occupancies of 0.818 (2) and 0.182 (2). The packing consists of chains of mol­ecules parallel to the a axis, connected by a bifurcated N—H⋯(O,N) hydrogen bond and a weak C(phen­yl)—H⋯O hydrogen bond. The packing is extended to a layer structure parallel to the ab plane by a weak C(phen­yl)—H⋯F hydrogen bond.
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spelling pubmed-29839082010-12-30 2-(2-Fluoro­biphenyl-4-yl)-N′-(propan-2-yl­idene)propanohydrazide Khanum, Saira Farman, Muhammad Rama, Nasim Hasan Hameed, Shahid Jones, Peter G. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(18)H(19)FN(2)O, the hydrazide side chain is approximately perpendicular to the central ring [dihedral angle = 76.80 (5)°]. The F atom is disordered over two positions with occupancies of 0.818 (2) and 0.182 (2). The packing consists of chains of mol­ecules parallel to the a axis, connected by a bifurcated N—H⋯(O,N) hydrogen bond and a weak C(phen­yl)—H⋯O hydrogen bond. The packing is extended to a layer structure parallel to the ab plane by a weak C(phen­yl)—H⋯F hydrogen bond. International Union of Crystallography 2010-03-17 /pmc/articles/PMC2983908/ /pubmed/21580681 http://dx.doi.org/10.1107/S1600536810009049 Text en © Khanum et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Khanum, Saira
Farman, Muhammad
Rama, Nasim Hasan
Hameed, Shahid
Jones, Peter G.
2-(2-Fluoro­biphenyl-4-yl)-N′-(propan-2-yl­idene)propanohydrazide
title 2-(2-Fluoro­biphenyl-4-yl)-N′-(propan-2-yl­idene)propanohydrazide
title_full 2-(2-Fluoro­biphenyl-4-yl)-N′-(propan-2-yl­idene)propanohydrazide
title_fullStr 2-(2-Fluoro­biphenyl-4-yl)-N′-(propan-2-yl­idene)propanohydrazide
title_full_unstemmed 2-(2-Fluoro­biphenyl-4-yl)-N′-(propan-2-yl­idene)propanohydrazide
title_short 2-(2-Fluoro­biphenyl-4-yl)-N′-(propan-2-yl­idene)propanohydrazide
title_sort 2-(2-fluoro­biphenyl-4-yl)-n′-(propan-2-yl­idene)propanohydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983908/
https://www.ncbi.nlm.nih.gov/pubmed/21580681
http://dx.doi.org/10.1107/S1600536810009049
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