Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)]

In the title compound, [Zn(C(10)H(14)O(4))(C(4)H(6)N(2))](n), each Zn(II) ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetra­hedral geometry. In one of the cap ligands, one methyl group is disordered between...

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Detalles Bibliográficos
Autores principales: Shi, Haochen, Li, Chunjie, Gao, Feng, Chen, Jingyan, Han, Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983912/
https://www.ncbi.nlm.nih.gov/pubmed/21580467
http://dx.doi.org/10.1107/S1600536810007105
Descripción
Sumario:In the title compound, [Zn(C(10)H(14)O(4))(C(4)H(6)N(2))](n), each Zn(II) ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetra­hedral geometry. In one of the cap ligands, one methyl group is disordered between positions 1 and 3 in a 0.518 (12):0.482 (12) ratio. Each cap ligand bridges three Zn(II) ions, forming two-dimensional layers, which inter­act further via N—H⋯O hydrogen bonds.

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