Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)]

In the title compound, [Zn(C(10)H(14)O(4))(C(4)H(6)N(2))](n), each Zn(II) ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetra­hedral geometry. In one of the cap ligands, one methyl group is disordered between...

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Detalles Bibliográficos
Autores principales: Shi, Haochen, Li, Chunjie, Gao, Feng, Chen, Jingyan, Han, Fei
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983912/
https://www.ncbi.nlm.nih.gov/pubmed/21580467
http://dx.doi.org/10.1107/S1600536810007105
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author Shi, Haochen
Li, Chunjie
Gao, Feng
Chen, Jingyan
Han, Fei
author_facet Shi, Haochen
Li, Chunjie
Gao, Feng
Chen, Jingyan
Han, Fei
author_sort Shi, Haochen
collection PubMed
description In the title compound, [Zn(C(10)H(14)O(4))(C(4)H(6)N(2))](n), each Zn(II) ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetra­hedral geometry. In one of the cap ligands, one methyl group is disordered between positions 1 and 3 in a 0.518 (12):0.482 (12) ratio. Each cap ligand bridges three Zn(II) ions, forming two-dimensional layers, which inter­act further via N—H⋯O hydrogen bonds.
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spelling pubmed-29839122010-12-30 Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)] Shi, Haochen Li, Chunjie Gao, Feng Chen, Jingyan Han, Fei Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [Zn(C(10)H(14)O(4))(C(4)H(6)N(2))](n), each Zn(II) ion is coordinated by one N atom from one 2-methyl-1H-imidazole ligand and three O atoms from two camphorate (cap) ligands in a distorted tetra­hedral geometry. In one of the cap ligands, one methyl group is disordered between positions 1 and 3 in a 0.518 (12):0.482 (12) ratio. Each cap ligand bridges three Zn(II) ions, forming two-dimensional layers, which inter­act further via N—H⋯O hydrogen bonds. International Union of Crystallography 2010-03-03 /pmc/articles/PMC2983912/ /pubmed/21580467 http://dx.doi.org/10.1107/S1600536810007105 Text en © Shi et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Shi, Haochen
Li, Chunjie
Gao, Feng
Chen, Jingyan
Han, Fei
Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)]
title Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)]
title_full Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)]
title_fullStr Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)]
title_full_unstemmed Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)]
title_short Poly[(μ(3)-camphorato-κ(3) O:O′:O′′)(2-methyl-1H-imidazole-κN (3))zinc(II)]
title_sort poly[(μ(3)-camphorato-κ(3) o:o′:o′′)(2-methyl-1h-imidazole-κn (3))zinc(ii)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983912/
https://www.ncbi.nlm.nih.gov/pubmed/21580467
http://dx.doi.org/10.1107/S1600536810007105
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