Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate

In the title oxopyrrolidine, C(15)H(19)NO(4), the five-membered pyrrolidine ring is in a twist conformation and its mean plane makes an angle of 89.2 (3)° with the phenyl ring. In the crystal, mol­ecules pack as dimers via strong O—H⋯O [R (2) (2)(10)] inter­actions cross-linked by weaker C—H⋯O and C...

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Detalles Bibliográficos
Autores principales: Gainsford, Graeme J., Mason, Jennifer M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983917/
https://www.ncbi.nlm.nih.gov/pubmed/21580760
http://dx.doi.org/10.1107/S1600536810010834
Descripción
Sumario:In the title oxopyrrolidine, C(15)H(19)NO(4), the five-membered pyrrolidine ring is in a twist conformation and its mean plane makes an angle of 89.2 (3)° with the phenyl ring. In the crystal, mol­ecules pack as dimers via strong O—H⋯O [R (2) (2)(10)] inter­actions cross-linked by weaker C—H⋯O and C—H⋯π inter­actions. Full synthetic and spectroscopic details are given for the title compound and related dicarboxyl­ates.

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