Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate

In the title oxopyrrolidine, C(15)H(19)NO(4), the five-membered pyrrolidine ring is in a twist conformation and its mean plane makes an angle of 89.2 (3)° with the phenyl ring. In the crystal, mol­ecules pack as dimers via strong O—H⋯O [R (2) (2)(10)] inter­actions cross-linked by weaker C—H⋯O and C...

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Detalles Bibliográficos
Autores principales: Gainsford, Graeme J., Mason, Jennifer M.
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983917/
https://www.ncbi.nlm.nih.gov/pubmed/21580760
http://dx.doi.org/10.1107/S1600536810010834
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author Gainsford, Graeme J.
Mason, Jennifer M.
author_facet Gainsford, Graeme J.
Mason, Jennifer M.
author_sort Gainsford, Graeme J.
collection PubMed
description In the title oxopyrrolidine, C(15)H(19)NO(4), the five-membered pyrrolidine ring is in a twist conformation and its mean plane makes an angle of 89.2 (3)° with the phenyl ring. In the crystal, mol­ecules pack as dimers via strong O—H⋯O [R (2) (2)(10)] inter­actions cross-linked by weaker C—H⋯O and C—H⋯π inter­actions. Full synthetic and spectroscopic details are given for the title compound and related dicarboxyl­ates.
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spelling pubmed-29839172010-12-30 Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate Gainsford, Graeme J. Mason, Jennifer M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title oxopyrrolidine, C(15)H(19)NO(4), the five-membered pyrrolidine ring is in a twist conformation and its mean plane makes an angle of 89.2 (3)° with the phenyl ring. In the crystal, mol­ecules pack as dimers via strong O—H⋯O [R (2) (2)(10)] inter­actions cross-linked by weaker C—H⋯O and C—H⋯π inter­actions. Full synthetic and spectroscopic details are given for the title compound and related dicarboxyl­ates. International Union of Crystallography 2010-03-27 /pmc/articles/PMC2983917/ /pubmed/21580760 http://dx.doi.org/10.1107/S1600536810010834 Text en © Gainsford and Mason 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gainsford, Graeme J.
Mason, Jennifer M.
Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate
title Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate
title_full Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate
title_fullStr Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate
title_full_unstemmed Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate
title_short Ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate
title_sort ethyl 1-benzyl-4-hydr­oxy-2-methyl-5-oxopyrrolidine-3-carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983917/
https://www.ncbi.nlm.nih.gov/pubmed/21580760
http://dx.doi.org/10.1107/S1600536810010834
work_keys_str_mv AT gainsfordgraemej ethyl1benzyl4hydroxy2methyl5oxopyrrolidine3carboxylate
AT masonjenniferm ethyl1benzyl4hydroxy2methyl5oxopyrrolidine3carboxylate

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