(4-Methyl­benzohydrazidato-κ(2) N′,O)[2-(4-methyl­benzoyl­hydrazinyl­idene-κ(2) N,O)-3-phenyl­propionato(2−)]oxido­vanadium(V) methanol monosolvate

The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl­hydrazidate anion and O,N,O′-chelated by the (benzoyl­hydrazono)propionate dianion. The octa­hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononu...

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Detalles Bibliográficos
Autores principales: Wong, Hon Wee, Lo, Kong Mun, Ng, Seik Weng
Formato: Texto
Lenguaje:English
Publicado: International Union of Crystallography 2010
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983918/
https://www.ncbi.nlm.nih.gov/pubmed/21580561
http://dx.doi.org/10.1107/S1600536810011372
Descripción
Sumario:The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoyl­hydrazidate anion and O,N,O′-chelated by the (benzoyl­hydrazono)propionate dianion. The octa­hedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent mol­ecules are linked by O—H⋯O and O—H⋯N hydrogen bonds, generating a centrosymmetric aggregate.

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