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(4-Methylbenzohydrazidato-κ(2) N′,O)[2-(4-methylbenzoylhydrazinylidene-κ(2) N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate
The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O′-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononu...
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| Formato: | Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2010
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983918/ https://www.ncbi.nlm.nih.gov/pubmed/21580561 http://dx.doi.org/10.1107/S1600536810011372 |
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| author | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_facet | Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng |
| author_sort | Wong, Hon Wee |
| collection | PubMed |
| description | The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O′-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent molecules are linked by O—H⋯O and O—H⋯N hydrogen bonds, generating a centrosymmetric aggregate. |
| format | Text |
| id | pubmed-2983918 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2010 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-29839182010-12-30 (4-Methylbenzohydrazidato-κ(2) N′,O)[2-(4-methylbenzoylhydrazinylidene-κ(2) N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The V(V) atom in the title compound, [V(C(8)H(9)N(2)O)(C(17)H(14)N(2)O(3))O]·CH(3)OH, is N,O-chelated by the benzoylhydrazidate anion and O,N,O′-chelated by the (benzoylhydrazono)propionate dianion. The octahedral trans-N(2)O(4) coordination geometry is completed by the vanadyl O atom. Two mononuclear complexes and two solvent molecules are linked by O—H⋯O and O—H⋯N hydrogen bonds, generating a centrosymmetric aggregate. International Union of Crystallography 2010-03-31 /pmc/articles/PMC2983918/ /pubmed/21580561 http://dx.doi.org/10.1107/S1600536810011372 Text en © Wong et al. 2010 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Wong, Hon Wee Lo, Kong Mun Ng, Seik Weng (4-Methylbenzohydrazidato-κ(2) N′,O)[2-(4-methylbenzoylhydrazinylidene-κ(2) N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate |
| title | (4-Methylbenzohydrazidato-κ(2)
N′,O)[2-(4-methylbenzoylhydrazinylidene-κ(2)
N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate |
| title_full | (4-Methylbenzohydrazidato-κ(2)
N′,O)[2-(4-methylbenzoylhydrazinylidene-κ(2)
N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate |
| title_fullStr | (4-Methylbenzohydrazidato-κ(2)
N′,O)[2-(4-methylbenzoylhydrazinylidene-κ(2)
N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate |
| title_full_unstemmed | (4-Methylbenzohydrazidato-κ(2)
N′,O)[2-(4-methylbenzoylhydrazinylidene-κ(2)
N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate |
| title_short | (4-Methylbenzohydrazidato-κ(2)
N′,O)[2-(4-methylbenzoylhydrazinylidene-κ(2)
N,O)-3-phenylpropionato(2−)]oxidovanadium(V) methanol monosolvate |
| title_sort | (4-methylbenzohydrazidato-κ(2)
n′,o)[2-(4-methylbenzoylhydrazinylidene-κ(2)
n,o)-3-phenylpropionato(2−)]oxidovanadium(v) methanol monosolvate |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983918/ https://www.ncbi.nlm.nih.gov/pubmed/21580561 http://dx.doi.org/10.1107/S1600536810011372 |
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