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Bis[μ-2,2′-dimethyl-1,1′-(oxydiethylene)bis(1H-benzimidazole)-κ(2) N (3):N (3′)]bis[bis(4-methoxybenzoato-κ(2) O,O′)cadmium(II)]
The title complex, [Cd(2)(C(8)H(7)O(3))(4)(C(20)H(22)N(4)O)(2)], forms a dimer of the paddle-wheel type, located on a crystallographic inversion centre. The Cd(II) ion is hexacoordinated by four carboxylate O atoms [Cd⋯O = 2.280 (2)–2.404 (2) Å] from two chelating 4-methoxybenzoate anions, and two...
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Formato: | Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2010
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC2983921/ https://www.ncbi.nlm.nih.gov/pubmed/21580526 http://dx.doi.org/10.1107/S1600536810009505 |
Sumario: | The title complex, [Cd(2)(C(8)H(7)O(3))(4)(C(20)H(22)N(4)O)(2)], forms a dimer of the paddle-wheel type, located on a crystallographic inversion centre. The Cd(II) ion is hexacoordinated by four carboxylate O atoms [Cd⋯O = 2.280 (2)–2.404 (2) Å] from two chelating 4-methoxybenzoate anions, and two N atoms [Cd⋯N = 2.313 (2) and 2.332 (2) Å] from one chelating 2,2′-dimethyl-3,3′-(oxydiethylene)bis(1H-benzimidazole) ligand. In the crystal, molecules are linked by a weak intermolecular C—H⋯O hydrogen bond and an intermolecular C—H⋯π interaction. |
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